C₆₁H₁₀₃ClO₁₁Si₃

Base Information

Chemical Name:C₆₁H₁₀₃ClO₁₁Si₃
CAS No.:1054791-63-7
Molecular Formula:C₆₁H₁₀₃ClO₁₁Si₃
Molecular Weight:1132.19
Hs Code.:

C<sub>61</sub>H<sub>103</sub>ClO<sub>11</sub>Si<sub>3</sub>

Synonyms:C₆₁H₁₀₃ClO₁₁Si₃

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Chemical Property of C₆₁H₁₀₃ClO₁₁Si₃

Chemical Property:

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Technology Process of C₆₁H₁₀₃ClO₁₁Si₃

There total 46 articles about C₆₁H₁₀₃ClO₁₁Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: (2R,4S,5R,6R)-2-{(S)-[(2R,3R,4R,5R,6R)-6-((E)-(S)-7-Chloro-4-hydroxy-2-methylene-octa-5,7-dienyl)-4,5-bis-(4-methoxy-benzyloxy)-3-methyl-tetrahydro-pyran-2-yl]-hydroxy-methyl}-6-(4-hydroxy-butyl)-2-methoxy-5-methyl-tetrahydro-pyran-4-ol

: 1054791-63-7
C₆₁H₁₀₃ClO₁₁Si₃

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<190::aid-anie190>3.0.co;2-0

Reference yield:

: 3-Methyl-1-triisopropylsilanyloxy-pent-4-en-2-ol

: 1054791-63-7
C₆₁H₁₀₃ClO₁₁Si₃

Guidance literature:: Multi-step reaction with 19 steps

1: 84 percent / NaH, TBAI / tetrahydrofuran / 0 - 20 °C

2: N-methylmorpholine N-oxide, OsO₄, H₂O / tetrahydrofuran

3: aq. NaIO₄ / methanol / 0 - 20 °C

4: toluene / -78 °C

5: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

6: Li, NH₃ / tetrahydrofuran / -78 °C

7: Et₃N / diethyl ether

8: hydrogen fluoride pyridine complex, pyridine / tetrahydrofuran

9: 92 percent / KOH / methanol

10: 87 percent / BuLi / -78 - 20 °C

11: 85 percent / Li, NH₃ / tetrahydrofuran / -78 °C

12: N-methylmorpholine N-oxide, OsO₄, H₂O / tetrahydrofuran

13: aq. NaIO₄ / methanol / 0 - 20 °C

14: 1.) diketene acetone adduct, Et₃N / 1.) hexane, 70 deg C, 2.) 125 deg C, 0.2 Torr

15: 1.) tert-BuLi, Bu₃SnCl, 2.) NIS, K₂CO₃ / 1.) THF, -78 to -30 deg C; -78 to 20 deg C, 2.) 0 deg C

16: 1.) tert-BuLi, MgBr₂ / 1.) Et₂O, -78 deg C, 2.) -78 to -50 deg C

17: 1.) NIS, CaCO₃, 2.) Bu₃SnH, AIBN / 1.) MeOH, THF, CH₃CN, 0-20 deg C, 2.) THF, PhBr, 80 deg C

18: 76 percent / TBAF / tetrahydrofuran

19: 75 percent / imidazole / dimethylformamide

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; potassium hydroxide; sodium periodate; N-iodo-succinimide; osmium(VIII) oxide; n-butyllithium; 2,2'-azobis(isobutyronitrile); diketene acetone; tributyltin chloride; tetrabutyl ammonium fluoride; ammonia; water; tert.-butyl lithium; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; lithium; sodium hydride; potassium carbonate; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; calcium carbonate; magnesium bromide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<190::aid-anie190>3.0.co;2-0

Reference yield:

: (2-Benzyloxy-3-methyl-pent-4-enyloxy)-triisopropyl-silane

: 1054791-63-7
C₆₁H₁₀₃ClO₁₁Si₃

Guidance literature:: Multi-step reaction with 18 steps

1: N-methylmorpholine N-oxide, OsO₄, H₂O / tetrahydrofuran

2: aq. NaIO₄ / methanol / 0 - 20 °C

3: toluene / -78 °C

4: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

5: Li, NH₃ / tetrahydrofuran / -78 °C

6: Et₃N / diethyl ether

7: hydrogen fluoride pyridine complex, pyridine / tetrahydrofuran

8: 92 percent / KOH / methanol

9: 87 percent / BuLi / -78 - 20 °C

10: 85 percent / Li, NH₃ / tetrahydrofuran / -78 °C

11: N-methylmorpholine N-oxide, OsO₄, H₂O / tetrahydrofuran

12: aq. NaIO₄ / methanol / 0 - 20 °C

13: 1.) diketene acetone adduct, Et₃N / 1.) hexane, 70 deg C, 2.) 125 deg C, 0.2 Torr

14: 1.) tert-BuLi, Bu₃SnCl, 2.) NIS, K₂CO₃ / 1.) THF, -78 to -30 deg C; -78 to 20 deg C, 2.) 0 deg C

15: 1.) tert-BuLi, MgBr₂ / 1.) Et₂O, -78 deg C, 2.) -78 to -50 deg C

16: 1.) NIS, CaCO₃, 2.) Bu₃SnH, AIBN / 1.) MeOH, THF, CH₃CN, 0-20 deg C, 2.) THF, PhBr, 80 deg C

17: 76 percent / TBAF / tetrahydrofuran

18: 75 percent / imidazole / dimethylformamide

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; potassium hydroxide; sodium periodate; N-iodo-succinimide; osmium(VIII) oxide; n-butyllithium; 2,2'-azobis(isobutyronitrile); diketene acetone; tributyltin chloride; tetrabutyl ammonium fluoride; ammonia; water; tert.-butyl lithium; tri-n-butyl-tin hydride; lithium; potassium carbonate; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; triethylamine; calcium carbonate; magnesium bromide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<190::aid-anie190>3.0.co;2-0