{(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium

Base Information

Chemical Name:{(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium
CAS No.:97396-46-8
Molecular Formula:C₂₆H₂₉NOPReSi
Molecular Weight:616.789
Hs Code.:

Synonyms:{(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium

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Chemical Property of {(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium

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Technology Process of {(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium

There total 1 articles about {(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: (η5-cyclopentadienyl)rhenium(NO)(PPh3)(hydride)

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 59350-94-6,121412-27-9
n-butyllithium-tetramethylethylenediamine

: 97396-46-8
{(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium

Guidance literature:: In tetrahydrofuran; Li-compd. and Re-complex reacted for 10 min at -15°C, trapped with Me3SiOSO2CF3; elem. anal.;
DOI:10.1039/c39850000283

Reference yield: 72.0%

: 97396-46-8
{(η5-cyclopentadienyl)(NO)(P(phenyl)3)(trimethylsilyl)}rhenium

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 333-27-7
methyl trifluoromethanesulfonate

: 115827-24-2
{(η5-trimethylsilylcyclopentadienyl)(NO)(P(phenyl)3)(methyl)}rhenium

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; Under N2, a soln. of (C5H5)Re(NO)(P(C6H5)3(Si(CH3)3) in THF is cooled to -78°C, a soln. of n-BuLi and TMEDA is added with stirring, after 2 h CH3OCTf is added, after 5 min solvents are removed.; NMR, residue is extd. (benzene), ext. is filtered, solvent is removed by rotary evapn., chromy., yellow band is collected, concd., dissolved (hexane), kept at -24°C (3 d), crystals are collected by filtration, dried under vac., elem. anal.;