{2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide

Base Information

• Chemical Name: {2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide
• CAS No.: 112714-53-1
• Molecular Formula: C₁₈H₂₀INOSn
• Molecular Weight: 511.977
• Mol file: 112714-53-1.mol

Synonyms:{2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide

Chemical Property of {2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide

Chemical Property:

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Technology Process of {2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide

There total 1 articles about {2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

{2-(2-oxo-N-pyrrolidinyl)ethyl}triphenyltin (123055-49-2) → {2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide (112714-53-1)

Guidance literature:

With I₂; In chloroform; addn. of I2 in CHCl3 to 4.06 mmol Sn-compound in CHCl3 over a period of 0.5 h;; concn.; dissolving of the oily residue in hot ethyl acetate/petroleum ether (1:1); crystallization on cooling; elem. anal.;;

DOI:10.1021/om00027a029

Reference yield: 81.0%

{2-(2-oxo-N-pyrrolidinyl)ethyl}diphenyltin iodide (112714-53-1) + sodium dimethyldithiocarbamate (128-04-1) → {2-(2-oxo-N-pyrrolidinyl)ethyl}(N,N-dimethyldithiocarbamato)diphenyltin

Guidance literature:

In ethanol; ethyl acetate; dissolving of Sn-compound and NaS2CN(CH3)2 in 1:1 ethanol/ethyl acetate; stirring at 50°C for 0.5 h, then at reflux for 0.5 h; cooling;; removal of solvent under vac.; partitioning of the solid between ethyl acetate and water; separation of organic layer; drying with MgSO4; concn.; cooling; elem. anal.;;

DOI:10.1021/om00027a029

upstream raw materials:

{2-(2-oxo-N-pyrrolidinyl)ethyl}triphenyltin

Refernces