{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

Base Information

Chemical Name:{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)
CAS No.:1397711-30-6
Molecular Formula:C₅₅H₃₆N₆O₂Zn
Molecular Weight:878.32
Hs Code.:

Synonyms:{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

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Chemical Property of {2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

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Technology Process of {2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

There total 3 articles about {2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1397711-06-6
{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

: 1397711-30-6
{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

Guidance literature:: {2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II); With pyridine; potassium hydroxide; In tetrahydrofuran; methanol; at 80 ℃; for 1h;

With citric acid; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1016/j.tet.2012.07.072

Reference yield:

: 110350-65-7
2-formyl-5,10,15,20-tetraphenylporphyrinato zinc(II)

: 1397711-30-6
{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride

2: potassium carbonate / toluene / 24 h / 120 °C / Inert atmosphere

3: pyridine; potassium hydroxide / tetrahydrofuran; methanol / 1 h / 80 °C

With pyridine; sodium hydride; potassium carbonate; potassium hydroxide; In tetrahydrofuran; methanol; toluene; 1: Wittig reaction;
DOI:10.1016/j.tet.2012.07.072

Reference yield:

: 58670-19-2
bromo-p-tolylhydrazono-acetic acid ethyl ester

: 1397711-30-6
{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / toluene / 24 h / 120 °C / Inert atmosphere

2: pyridine; potassium hydroxide / tetrahydrofuran; methanol / 1 h / 80 °C

With pyridine; potassium carbonate; potassium hydroxide; In tetrahydrofuran; methanol; toluene;
DOI:10.1016/j.tet.2012.07.072