{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

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Chemical Name:{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)
CAS No.:1397711-06-6
Molecular Formula:C₅₇H₄₂N₆O₂Zn
Molecular Weight:908.389
Hs Code.:

Synonyms:{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

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Chemical Property of {2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

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Technology Process of {2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

There total 1 articles about {2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 110350-65-7
2-formyl-5,10,15,20-tetraphenylporphyrinato zinc(II)

: 1397711-06-6
{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride

2: potassium carbonate / toluene / 24 h / 120 °C / Inert atmosphere

With sodium hydride; potassium carbonate; In toluene; 1: Wittig reaction;
DOI:10.1016/j.tet.2012.07.072

Reference yield: 100.0%

: 1397711-06-6
{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

: 2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrin

Guidance literature:: With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 0.25h;
DOI:10.1016/j.tet.2012.07.072

Reference yield: 86.0%

: 1397711-06-6
{2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

: 1397711-30-6
{2-[3-carboxy-1-(p-tolyl)-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II)

Guidance literature:: {2-[3-ethoxycarbonyl-1-(p-tolyl)-4,5-dihydro-1H-pyrazol-5-yl]-5,10,15,20-tetraphenylporphyrinato}zinc(II); With pyridine; potassium hydroxide; In tetrahydrofuran; methanol; at 80 ℃; for 1h;

With citric acid; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1016/j.tet.2012.07.072