[Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)

Base Information

• Chemical Name: [Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)
• CAS No.: 864411-24-5
• Molecular Formula: CF₃O₃S*C₂₉H₁₉N₃O₃Re
• Molecular Weight: 792.766
• Mol file: 864411-24-5.mol

Synonyms:[Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)

Chemical Property of [Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃)

There total 2 articles about [Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bathophenanthroline (1662-01-7) → [Re(4,7-diphenyl-1,10-phenanthroline)(CO)3(CH3CN)](CF3SO3) (864411-24-5)

Guidance literature:

Multi-step reaction with 2 steps

1: n-heptane

2: acetonitrile

In n-heptane; acetonitrile;

DOI:10.1039/b712995e

Reference yield:

Re(CO)3Br((phenyl)2C12H6N2) + silver trifluoromethanesulfonate (2923-28-6) + acetonitrile (75-05-8,26809-02-9) → [Re(4,7-diphenyl-1,10-phenanthroline)(CO)3(CH3CN)](CF3SO3) (864411-24-5)

Guidance literature:

In acetonitrile; (N2); treatment of rhenium compd. with silver triflate in acetonitrile at room temp.;

DOI:10.1039/b712995e

Reference yield: 79.0%

[Re(4,7-diphenyl-1,10-phenanthroline)(CO)3(CH3CN)](CF3SO3) (864411-24-5) + N-[2-(3-indolyl)ethyl]nicotinamide (29876-14-0) + water (7732-18-5) + acetonitrile (75-05-8,26809-02-9) → [Re(4,7-diphenyl-1,10-phenanthroline)(CO)3(N-(3-pyridoyl)tryptamine)](CF3SO3)*H2O*0.25(acetonitrile)

Guidance literature:

In tetrahydrofuran; a mixt. of Re complex and ligand in THF refluxed under N2; evapd., recrystd. (MeCN/acetone/Et2O); elem. anal.;

DOI:10.1021/ic050531u

upstream raw materials:

silver trifluoromethanesulfonate

acetonitrile

bathophenanthroline

Downstream raw materials:

[(4,7-diphenyl-1,10-phenanthroline)(CO)3(N-(3-pyridyl)maleimide)rhenium(I)](CF₃SO₃)

[Re(4,7-diphenyl-1,10-phenanthroline)(CO)₃(3,4-diaminopyridine)](CF₃SO₃)