C₅₆H₇₄O₁₆Si

Base Information

Chemical Name:C₅₆H₇₄O₁₆Si
CAS No.:306726-37-4
Molecular Formula:C₅₆H₇₄O₁₆Si
Molecular Weight:1031.28
Hs Code.:

C<sub>56</sub>H<sub>74</sub>O<sub>16</sub>Si

Synonyms:C₅₆H₇₄O₁₆Si

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Chemical Property of C₅₆H₇₄O₁₆Si

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Technology Process of C₅₆H₇₄O₁₆Si

There total 46 articles about C₅₆H₇₄O₁₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 582-25-2
Potassium benzoate

: 306726-36-3
C₄₉H₆₈O₁₇SSi

: 306726-37-4
C₅₆H₇₄O₁₆Si

Guidance literature:: Potassium benzoate; C₄₉H₆₈O₁₇SSi; With 18-crown-6 ether; In N,N-dimethyl-formamide; at 120 ℃; for 1h;

With sulfuric acid; In tetrahydrofuran; at 0 ℃; for 0.5h;
DOI:10.1002/1521-3765(20000901)6:17<3116::AID-CHEM3116>3.0.CO;2-8

Reference yield:

: 256341-98-7
(3aR,4S,7R,7aS)-2,2-Dimethyl-4-phenylselanyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-ol

: 306726-37-4
C₅₆H₇₄O₁₆Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: NaH / dimethylformamide / 0.08 h / 0 °C

1.2: 95 percent / nBu₄NI / dimethylformamide / 2 h / 0 - 25 °C

2.1: 96 percent / PPTS; MeOH / 1 h / 25 °C

3.1: 91 percent / 2,6-lutidine / tetrahydrofuran / 0.5 h / -78 °C

4.1: 100 percent / DAST / CH₂Cl₂ / 0.5 h / 0 °C

5.1: 92 percent / SnCl₂ / diethyl ether / 3 h / 0 - 25 °C

6.1: 98 percent / K₂CO₃; MeOH / diethyl ether / 1 h / 25 °C

7.1: 70 percent / TBAF / tetrahydrofuran / 0.25 h / 0 °C

8.1: aq. NaIO₄; NaHCO₃ / methanol; CH₂Cl₂ / 4 h / 25 °C

9.1: 95 mg / iPr₂NH; vinyl acetate / toluene / 12 h / 140 °C

10.1: 65 percent / NMO; H₂O; OsO₄ / quinuclidine / acetone / 24 h / 25 °C

11.1: SOCl₂; Ey₃N / CH₂Cl₂ / 0.08 h / 0 °C

12.1: 62 mg / aq. NaIO₄; NaHCO₃ / acetonitrile; CCl₄ / 1 h / 0 - 25 °C

13.1: 18-crown-6 / dimethylformamide / 1 h / 120 °C

13.2: 76 percent / aq. H₂SO₄ / tetrahydrofuran / 0.5 h / 0 °C

With 2,6-dimethylpyridine; methanol; sodium periodate; osmium(VIII) oxide; thionyl chloride; vinyl acetate; N-methyl-2-indolinone; 18-crown-6 ether; tetrabutyl ammonium fluoride; water; pyridinium p-toluenesulfonate; sodium hydride; sodium hydrogencarbonate; potassium carbonate; triethylamine; diisopropylamine; 4,4'-diaminostilbene-2,2'-disulfonic acid; tin(ll) chloride; Quinuclidine; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; 1.1: Metallation / 1.2: Etherification / 2.1: Ring cleavage / 3.1: Etherification / 4.1: Rearrangement / 5.1: Glycosidation / 6.1: Deacylation / 7.1: Silyl ether cleavage / 8.1: Oxidation / 9.1: Cyclization / 10.1: Oxidation / 11.1: Cyclization / 12.1: Oxidation / 13.1: Ring cleavage / 13.2: Hydrolysis;
DOI:10.1002/1521-3765(20000901)6:17<3116::AID-CHEM3116>3.0.CO;2-8

Reference yield:

: 374115-40-9
phenyl 1-seleno-β-D-xylopyranoside

: 306726-37-4
C₅₆H₇₄O₁₆Si

Guidance literature:: Multi-step reaction with 14 steps

1.1: 51.92 g / TFA / dimethylformamide / 3 h / 45 °C

2.1: NaH / dimethylformamide / 0.08 h / 0 °C

2.2: 95 percent / nBu₄NI / dimethylformamide / 2 h / 0 - 25 °C

3.1: 96 percent / PPTS; MeOH / 1 h / 25 °C

4.1: 91 percent / 2,6-lutidine / tetrahydrofuran / 0.5 h / -78 °C

5.1: 100 percent / DAST / CH₂Cl₂ / 0.5 h / 0 °C

6.1: 92 percent / SnCl₂ / diethyl ether / 3 h / 0 - 25 °C

7.1: 98 percent / K₂CO₃; MeOH / diethyl ether / 1 h / 25 °C

8.1: 70 percent / TBAF / tetrahydrofuran / 0.25 h / 0 °C

9.1: aq. NaIO₄; NaHCO₃ / methanol; CH₂Cl₂ / 4 h / 25 °C

10.1: 95 mg / iPr₂NH; vinyl acetate / toluene / 12 h / 140 °C

11.1: 65 percent / NMO; H₂O; OsO₄ / quinuclidine / acetone / 24 h / 25 °C

12.1: SOCl₂; Ey₃N / CH₂Cl₂ / 0.08 h / 0 °C

13.1: 62 mg / aq. NaIO₄; NaHCO₃ / acetonitrile; CCl₄ / 1 h / 0 - 25 °C

14.1: 18-crown-6 / dimethylformamide / 1 h / 120 °C

14.2: 76 percent / aq. H₂SO₄ / tetrahydrofuran / 0.5 h / 0 °C

With 2,6-dimethylpyridine; methanol; sodium periodate; osmium(VIII) oxide; thionyl chloride; vinyl acetate; N-methyl-2-indolinone; 18-crown-6 ether; tetrabutyl ammonium fluoride; water; pyridinium p-toluenesulfonate; sodium hydride; sodium hydrogencarbonate; potassium carbonate; triethylamine; diisopropylamine; 4,4'-diaminostilbene-2,2'-disulfonic acid; trifluoroacetic acid; tin(ll) chloride; Quinuclidine; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; 1.1: Cyclization / 2.1: Metallation / 2.2: Etherification / 3.1: Ring cleavage / 4.1: Etherification / 5.1: Rearrangement / 6.1: Glycosidation / 7.1: Deacylation / 8.1: Silyl ether cleavage / 9.1: Oxidation / 10.1: Cyclization / 11.1: Oxidation / 12.1: Cyclization / 13.1: Oxidation / 14.1: Ring cleavage / 14.2: Hydrolysis;
DOI:10.1002/1521-3765(20000901)6:17<3116::AID-CHEM3116>3.0.CO;2-8