(E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

Base Information

Chemical Name:(E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol
CAS No.:233750-62-4
Molecular Formula:C₁₈H₃₀O₂Si
Molecular Weight:306.521
Hs Code.:

Synonyms:(E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

Chemical Property:

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Technology Process of (E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

There total 3 articles about (E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 161912-62-5
(3R,4S,5E)-3-hydroxy-2,4-dimethylhepta-1,5-diene

: 233750-62-4
(E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / Sharpless reagent, D-DET

2: 96 percent / imidazole

3: 1.) CuI, 2.) K₂CO₃ / 1.) THF, from -50 deg C to RT, 2.) MeOH

With 1H-imidazole; copper(l) iodide; diethyl (2S,3S)-tartrate; Sharpless reagent; potassium carbonate;
DOI:10.1021/ja9904686

Reference yield:

: 233750-72-6
(E)-(1R,2S)-2-Methyl-1-((S)-2-methyl-oxiranyl)-pent-3-en-1-ol

: 233750-62-4
(E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / imidazole

2: 1.) CuI, 2.) K₂CO₃ / 1.) THF, from -50 deg C to RT, 2.) MeOH

With 1H-imidazole; copper(l) iodide; potassium carbonate;
DOI:10.1021/ja9904686

Reference yield:

: 107735-20-6
[(dimethylphenylsilyl)methyl]magnesium chloride

: 233750-73-7
Trimethyl-[(E)-(1R,2S)-2-methyl-1-((S)-2-methyl-oxiranyl)-pent-3-enyloxy]-silane

: 233750-62-4
(E)-(3S,4R,5S)-1-(Dimethyl-phenyl-silanyl)-3,5-dimethyl-oct-6-ene-3,4-diol

Guidance literature:: With copper(l) iodide; potassium carbonate; Yield given; Multistep reaction; 1.) THF, from -50 deg C to RT, 2.) MeOH;
DOI:10.1021/ja9904686