(+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

Base Information

Chemical Name:(+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate
CAS No.:114819-62-4
Molecular Formula:C₂₄H₃₅O₆PSi
Molecular Weight:478.598
Hs Code.:

Synonyms:(+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

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Technology Process of (+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

There total 5 articles about (+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 1623-08-1
phosphoric acid dibenzyl ester

: 114790-32-8
3-diazo-1-<(tert-butyldimethylsilyl)oxy>-2-butanone

: 114819-62-4
(+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

Guidance literature:: In benzene; for 2h; Ambient temperature;
DOI:10.1021/jo00250a010

Reference yield:

: 105459-05-0
{[tert-butyl(dimethyl)silyl]oxy}acetic acid

: 114819-62-4
(+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

Guidance literature:: Multi-step reaction with 3 steps

1: oxalyl chloride / benzene / 1.) RT, 30 min, 2.) reflux, 30 min

2: benzene; diethyl ether / Ambient temperature

3: 53 percent / benzene / 2 h / Ambient temperature

With oxalyl dichloride; In diethyl ether; benzene;
DOI:10.1021/jo00250a010

Reference yield:

: 114790-31-7
n-butyl <(tert-butyldimethylsilyl)oxy>acetate

: 114819-62-4
(+/-)-dibenzyl 4-<(tert-butyldimethylsilyl)oxy>-3-oxo-2-butyl phosphate

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / potassium hydroxide / tetrahydrofuran; methanol; H₂O / 0.5 h / -10 - 5 °C

2: oxalyl chloride / benzene / 1.) RT, 30 min, 2.) reflux, 30 min

3: benzene; diethyl ether / Ambient temperature

4: 53 percent / benzene / 2 h / Ambient temperature

With potassium hydroxide; oxalyl dichloride; In tetrahydrofuran; methanol; diethyl ether; water; benzene;
DOI:10.1021/jo00250a010