C₆₀H₈₆O₁₁Si₂

Base Information

Chemical Name:C₆₀H₈₆O₁₁Si₂
CAS No.:132375-93-0
Molecular Formula:C₆₀H₈₆O₁₁Si₂
Molecular Weight:1039.51
Hs Code.:

C<sub>60</sub>H<sub>86</sub>O<sub>11</sub>Si<sub>2</sub>

Synonyms:C₆₀H₈₆O₁₁Si₂

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Chemical Property of C₆₀H₈₆O₁₁Si₂

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Technology Process of C₆₀H₈₆O₁₁Si₂

There total 65 articles about C₆₀H₈₆O₁₁Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 132375-92-9
C₅₄H₇₂O₁₁Si

: 132375-93-0
C₆₀H₈₆O₁₁Si₂

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; for 0.333333h;

Reference yield:

: 132375-34-9
2-[(4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-ethanol

: 132375-93-0
C₆₀H₈₆O₁₁Si₂

Guidance literature:: Multi-step reaction with 28 steps

1: 84 percent / I₂, PPh₃, imidazole / acetonitrile / 0.5 h / 25 °C

2: 90 percent / acetonitrile / 48 h / 80 °C

3: 1) n-BuLi / 1) THF, -78 deg C, 1 h, 2) HMPA, -78 deg C - 25 deg C, 18 h

4: 98 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / 25 °C

5: 74 percent / AgCO₄, NaHCO₃, 4 Angstroem molecular sieve, silicagel / nitromethane / 4 h / 25 °C

6: 95 percent / Ph₃SnH, AIBN / toluene / 2 h / 110 °C

7: 85 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

8: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

9: DBU / dimethylformamide / 2 h / 145 °C

10: m-chloroperbenzoic acid / tetrahydrofuran; H₂O / 1 h / 0 - 25 °C

11: NaBH₄ / methanol / 1 h / 0 °C

12: 1) NaIO₄, 2) NaBH₄ / 1) EtOH, H₂O, 25 deg C, 1 h, 2) MeOH, 0 deg C, 1 h

13: 82 percent / pyridine / 4 h / -20 - 0 °C

14: 97 percent / imidazole / dimethylformamide / 12 h / 25 °C

15: 98 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

16: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

17: NaI / acetone / 2 h / 56 °C

18: 92 percent / iodine / acetonitrile / 48 h / 60 °C

19: 1) n-BuLi, 2) HMPA / 1) THF, -78 - 0 deg C, 20 min, 2) -78 - 25 deg C, 3 h

20: tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 25 °C

21: imidazole / dimethylformamide / 3 h / 0 °C

22: 87 percent / AgClO₄, NaHCO₃, silicagel, 3 Angstroem molecular sieve / nitromethane / 3 h / 25 °C

23: m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 0 °C

24: CH₂Cl₂ / 0.5 h / -78 °C

25: 90 percent / EtSH, Zn(OTf)2, NaHCO₃ / CH₂Cl₂ / 5 h / 25 °C

26: 86 percent / pyridine / 12 h / 0 °C

27: 75 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 3 h / 0 °C

28: 82 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / 0 °C

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; sodium periodate; n-butyllithium; 2,2'-azobis(isobutyronitrile); 3 A molecular sieve; 4 A molecular sieve; triphenylstannane; tetrabutyl ammonium fluoride; iodine; silver perchlorate; silica gel; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; ethanethiol; sodium iodide; In tetrahydrofuran; methanol; nitromethane; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile;

Reference yield:

: 132375-35-0
tert-Butyl-[(4S,5R)-4-(2-iodo-ethyl)-2-phenyl-[1,3]dioxan-5-yloxy]-dimethyl-silane

: 132375-93-0
C₆₀H₈₆O₁₁Si₂

Guidance literature:: Multi-step reaction with 27 steps

1: 90 percent / acetonitrile / 48 h / 80 °C

2: 1) n-BuLi / 1) THF, -78 deg C, 1 h, 2) HMPA, -78 deg C - 25 deg C, 18 h

3: 98 percent / tetrabutylammonium fluoride / tetrahydrofuran / 12 h / 25 °C

4: 74 percent / AgCO₄, NaHCO₃, 4 Angstroem molecular sieve, silicagel / nitromethane / 4 h / 25 °C

5: 95 percent / Ph₃SnH, AIBN / toluene / 2 h / 110 °C

6: 85 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

7: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

8: DBU / dimethylformamide / 2 h / 145 °C

9: m-chloroperbenzoic acid / tetrahydrofuran; H₂O / 1 h / 0 - 25 °C

10: NaBH₄ / methanol / 1 h / 0 °C

11: 1) NaIO₄, 2) NaBH₄ / 1) EtOH, H₂O, 25 deg C, 1 h, 2) MeOH, 0 deg C, 1 h

12: 82 percent / pyridine / 4 h / -20 - 0 °C

13: 97 percent / imidazole / dimethylformamide / 12 h / 25 °C

14: 98 percent / DIBAH / CH₂Cl₂ / 1 h / -78 °C

15: NEt₃ / CH₂Cl₂ / 1 h / 0 °C

16: NaI / acetone / 2 h / 56 °C

17: 92 percent / iodine / acetonitrile / 48 h / 60 °C

18: 1) n-BuLi, 2) HMPA / 1) THF, -78 - 0 deg C, 20 min, 2) -78 - 25 deg C, 3 h

19: tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 25 °C

20: imidazole / dimethylformamide / 3 h / 0 °C

21: 87 percent / AgClO₄, NaHCO₃, silicagel, 3 Angstroem molecular sieve / nitromethane / 3 h / 25 °C

22: m-chloroperbenzoic acid, NaHCO₃ / CH₂Cl₂ / 0 °C

23: CH₂Cl₂ / 0.5 h / -78 °C

24: 90 percent / EtSH, Zn(OTf)2, NaHCO₃ / CH₂Cl₂ / 5 h / 25 °C

25: 86 percent / pyridine / 12 h / 0 °C

26: 75 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 3 h / 0 °C

27: 82 percent / 2,6-lutidine / CH₂Cl₂ / 0.33 h / 0 °C

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; sodium periodate; n-butyllithium; 2,2'-azobis(isobutyronitrile); 3 A molecular sieve; 4 A molecular sieve; triphenylstannane; tetrabutyl ammonium fluoride; iodine; silver perchlorate; silica gel; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; ethanethiol; sodium iodide; In tetrahydrofuran; methanol; nitromethane; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; acetonitrile;