Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

Base Information

Chemical Name:Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester
CAS No.:237075-30-8
Molecular Formula:C₂₀H₂₈O₆
Molecular Weight:364.439
Hs Code.:

Synonyms:Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

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Chemical Property of Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

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Technology Process of Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

There total 11 articles about Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 237075-23-9
2,2-dimethyl-4-(3-methylbut-3-enyl)[1,3]dioxolane

: 237075-30-8
Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 11 steps

1: Br₂, KHMDS / diethyl ether / -78 °C

2: 1.) O₃, 2.) Ph₃P

3: KOH

4: 1.) t-BuLi, Bu₃SnLi, 3.) n-BuLi, CuCN,

6: MCPBA

7: TBAF, NH₄Cl

8: Ag₂O

9: L-selectride

11: H₂O, H(+)

With potassium hydroxide; n-butyllithium; tri-n-butyltin lithium; tetrabutyl ammonium fluoride; water; bromine; tert.-butyl lithium; hydrogen cation; potassium hexamethylsilazane; L-Selectride; ammonium chloride; ozone; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; silver(l) oxide; In diethyl ether;
DOI:10.1021/ja990784k

Reference yield:

: 237075-36-4
Benzoic acid (5S,6S,7S,8R)-6-[(E)-4-(tert-butyl-dimethyl-silanyloxy)-1-methyl-but-1-enyl]-7-methoxy-2,2-dimethyl-1,3-dioxa-spiro[4.5]dec-8-yl ester

: 237075-30-8
Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

Guidance literature:: With water; hydrogen cation; Yield given;
DOI:10.1021/ja990784k

Reference yield:

: 237075-22-8
(S)-2,2-Dimethyl-1,3-dioxa-spiro[4.5]dec-6-en-8-one

: 237075-30-8
Benzoic acid (1R,2S,3S,4S)-4-hydroxy-4-hydroxymethyl-3-((E)-4-hydroxy-1-methyl-but-1-enyl)-2-methoxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) t-BuLi, Bu₃SnLi, 3.) n-BuLi, CuCN,

3: MCPBA

4: TBAF, NH₄Cl

5: Ag₂O

6: L-selectride

8: H₂O, H(+)

With n-butyllithium; tri-n-butyltin lithium; tetrabutyl ammonium fluoride; water; tert.-butyl lithium; hydrogen cation; L-Selectride; ammonium chloride; 3-chloro-benzenecarboperoxoic acid; silver(l) oxide;
DOI:10.1021/ja990784k