(1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

Base Information

Chemical Name:(1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol
CAS No.:116706-51-5
Molecular Formula:C₂₈H₅₀O₅Si
Molecular Weight:494.788
Hs Code.:

Synonyms:(1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

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Chemical Property of (1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

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Technology Process of (1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

There total 1 articles about (1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 116706-46-8
2-<(1S,2E)-1-methoxy-2-butenyl>-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 116706-50-4
(2S,3S,4S,5S)-5-(tert-Butyldimethylsilyloxy)-3-(p-methoxybenzyloxy)-2,4-dimethylheptanal

: 116706-51-5
(1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

: 116782-60-6
(1E,3S,4S,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

Guidance literature:: With triethanolamine; Yield given. Multistep reaction. Yields of byproduct given; 1) toluene, 4 kbar, 12 h, 2) CH₂Cl₂, 12 h;

Reference yield: 85.0%

: 116706-51-5
(1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

: 135393-87-2
(2R,4R,5R,6R)-4-<(1S,2S)-2-(tert-Butyldimethylsiloxy)-1-methylbutyl>-6-<(1R,2Z)-3-methoxy-1-methyl-2-propenyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxane

Guidance literature:: With 4 A molecular sieve; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; for 0.25h; Ambient temperature;

Reference yield:

: 116706-51-5
(1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol

: 135501-19-8
(2R,3S,4R,6R,8E)-2-((2R,4R,5R,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-5-one

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / DDQ, molecular sieves 4 Angstroem / CH₂Cl₂ / 0.25 h / Ambient temperature

2: 1) O₃, 2) Zn-powder, HOAc, H₂O / 1) CH₂Cl₂, -85 deg C, 2) 0 deg C to r.t. over 2 h

With 4 A molecular sieve; water; ozone; acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; zinc; In dichloromethane;