116706-50-4

Upstream product

• 119003-95-1 (3R,4R,5S,6S)-6-(tert-Butyldimethylsilyloxy)-4-(p-methoxybenzyloxy)-3,5-dimethyl-1-octene 
• 119003-94-0 (3R,4R,5S,6S)-6-(tert-Butyldimethylsilyloxy)-3,5-dimethyl-1-octen-4-ol 
• 108815-17-4 (2S,3S)-3-<(tertbutyl)dimethylsilyloxy>-2-methylpentanal 
• 2746-25-0 p-Methoxybenzyl bromide 

Downstream Products

• 135393-92-9 (2S,4S,6R,8E)-2-((2S,4S,5S,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-3,5-dione 
• 135501-24-5 (2S,4R,6R,8E)-2-((2S,4S,5S,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-3,5-dione 
• 135501-21-2 (2S,4RS,6S,8E)-2-((2S,4S,5S,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-3,5-dione 
• 135501-20-1 (2R,3S,4R,6S,8E)-2-((2R,4R,5R,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-5-one 
• 135501-19-8 (2R,3S,4R,6R,8E)-2-((2R,4R,5R,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-5-one 
• 135393-89-4 (2S,4RS,6R,8E)-2-((2S,4S,5S,6R)-2-(p-Methoxyphenyl)-5-methyl-6-<(1S)-1-methyl-2-oxobutyl>-1,3-dioxan-4-yl)-4,6,8-trimethyl-8-undecen-3,5-dione 
• 135393-93-0 (2R,3S,4R,6R,8E)-2-((2S,4R,5S,6S)-6-<(1R,2S)-2-Hydroxy-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)-3-hydroxy-4,6,8-trimethyl-8-undecen-5-one 
• 135393-87-2 (2R,4R,5R,6R)-4-<(1S,2S)-2-(tert-Butyldimethylsiloxy)-1-methylbutyl>-6-<(1R,2Z)-3-methoxy-1-methyl-2-propenyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxane 
• 135393-99-6 (2S)-2-((2S,4S,5S,6R)-6-<(1S,2S)-2-(tert-Butyldimethylsilyloxy)-1-methylbutyl>-2-(p-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)propanal 
• 116706-51-5 (1Z,3R,4R,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol 
• 116782-60-6 (1E,3S,4S,5R,6R,7S,8S)-8-(tert-Butyldimethylsiloxy)-1-methoxy-6-(p-methoxybenzyloxy)-3,5,7-trimethyl-1-decen-4-ol 

Relevant academic research and scientific papers

Stereoselective Synthesis of Alcohols, XXVIII. - Stereocontrol of Addition of Chiral (E)-(α-Chlorocrotyl)boronates to Chiral Aldehydes

On reaction of the chiral (E)-(α-chlorocrotyl)boronates 5 with chiral aldehydes 1, the diastereoselectivity depends on whether the asymmetric induction of the reagent and the substrate cooperate (matched pair) or whether they are opposed (mismatched pair)