alpha-D-Glucopyranose, 6-azido-6-deoxy-

Base Information

• Chemical Name: alpha-D-Glucopyranose, 6-azido-6-deoxy-
• CAS No.: 138331-98-3
• Molecular Formula: C6H11N3O5
• Molecular Weight: 205.1686
• DSSTox Substance ID: DTXSID70160584
• Wikidata: Q83028940
• Mol file: 138331-98-3.mol

Synonyms:alpha-D-Glucopyranose, 6-azido-6-deoxy-;138331-98-3;6-Azido-6-deoxy-alpha-D-glucopyranose;CCRIS 4989;alpha -D-Mannopyranosyl azide;DTXSID70160584

Chemical Property of alpha-D-Glucopyranose, 6-azido-6-deoxy-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: -1.6
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 2
• Exact Mass: 205.06987046
• Heavy Atom Count: 14
• Complexity: 244

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)O)O)O)O)N=[N+]=[N-]
• Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)O)O)O)O)N=[N+]=[N-]

Technology Process of alpha-D-Glucopyranose, 6-azido-6-deoxy-

There total 4 articles about alpha-D-Glucopyranose, 6-azido-6-deoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,2,3,4-Tetra-O-acetyl-6-azido-6-desoxy-α-D-glucopyranose (51642-43-4) → 6-azido-α-D-6-deoxy-glucopyranose (138331-98-3,138332-00-0,138332-01-1)

Guidance literature:

With methanol; sodium methylate; at 20 ℃;

Reference yield:

6-O-Tosyl-α-D-glucopyranose (26391-80-0) → 6-azido-α-D-6-deoxy-glucopyranose (138331-98-3,138332-00-0,138332-01-1)

Guidance literature:

With sodium azide;

DOI:10.1016/0960-894X(96)00484-2

Reference yield:

D-Glucose (2280-44-6) → 6-azido-α-D-6-deoxy-glucopyranose (138331-98-3,138332-00-0,138332-01-1)

Guidance literature:

Multi-step reaction with 2 steps

2: NaN₃

With sodium azide;

DOI:10.1016/0960-894X(96)00484-2

upstream raw materials:

6-O-Tosyl-α-D-glucopyranose

D-Glucose

1,2,3,4-Tetra-O-acetyl-6-azido-6-desoxy-α-D-glucopyranose