C₃₇H₄₈O₆SSi

Base Information

Chemical Name:C₃₇H₄₈O₆SSi
CAS No.:113133-01-0
Molecular Formula:C₃₇H₄₈O₆SSi
Molecular Weight:648.936
Hs Code.:

C<sub>37</sub>H<sub>48</sub>O<sub>6</sub>SSi

Synonyms:C₃₇H₄₈O₆SSi

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₃₇H₄₈O₆SSi

Chemical Property:

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Technology Process of C₃₇H₄₈O₆SSi

There total 7 articles about C₃₇H₄₈O₆SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 113133-00-9
C₃₁H₃₄O₆S

: 113133-01-0
C₃₇H₄₈O₆SSi

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 33 ℃; for 24h;
DOI:10.1021/jo00243a001

Reference yield:

: 113132-92-6
3,3-Dimethyl-10-trimethylsilanyl-1,5-dioxa-spiro[5.5]undec-8-ene-9-carbonitrile

: 113133-01-0
C₃₇H₄₈O₆SSi

Guidance literature:: Multi-step reaction with 7 steps

1: 86 percent / i-Bu₂AlH (Dibal) / CH₂Cl₂; hexane / 5 h / -78 °C

2: 1.) NaH / 1.) THF, 30 min, 2.) THF, RT, 5.5 h

3: 99 percent / i-Bu₂AlH (Dibal) / CH₂Cl₂; hexane / 1.5 h / -78 °C

4: 89 percent / n-Bu₃P / tetrahydrofuran / 1 h / Ambient temperature

5: 2.) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / 1.) toluene, 134 deg C, 72 h, 2.) dioxane, 70 deg C, 15.5 h

6: 95 percent / tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF), (MeO)3P, O₂ / acetonitrile / 0.83 h / -37 °C

7: 92 percent / imidazole / dimethylformamide / 24 h / 33 °C

With 1H-imidazole; tributylphosphine; tris(dimethylamino)sulfonium trimethylsilyldifluoride; oxygen; sodium hydride; diisobutylaluminium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; phosphorous acid trimethyl ester; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00243a001

Reference yield:

: 113132-93-7
3,3-Dimethyl-10-trimethylsilanyl-1,5-dioxa-spiro[5.5]undec-8-ene-9-carbaldehyde

: 113133-01-0
C₃₇H₄₈O₆SSi

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) NaH / 1.) THF, 30 min, 2.) THF, RT, 5.5 h

2: 99 percent / i-Bu₂AlH (Dibal) / CH₂Cl₂; hexane / 1.5 h / -78 °C

3: 89 percent / n-Bu₃P / tetrahydrofuran / 1 h / Ambient temperature

4: 2.) 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / 1.) toluene, 134 deg C, 72 h, 2.) dioxane, 70 deg C, 15.5 h

5: 95 percent / tris(dimethylamino)sulfonium difluorotrimethylsilicate (TASF), (MeO)3P, O₂ / acetonitrile / 0.83 h / -37 °C

6: 92 percent / imidazole / dimethylformamide / 24 h / 33 °C

With 1H-imidazole; tributylphosphine; tris(dimethylamino)sulfonium trimethylsilyldifluoride; oxygen; sodium hydride; diisobutylaluminium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; phosphorous acid trimethyl ester; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00243a001