Au⁽¹⁺⁾P(C₆H₅)3C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅)

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Chemical Name:Au⁽¹⁺⁾*P(C₆H₅)3*C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅)
CAS No.:21135-20-6
Molecular Formula:Au*C₅H₅*C₁₈H₁₅P
Molecular Weight:524.352
Hs Code.:
Mol file:21135-20-6.mol

Au<sup>(1+)</sup>*P(C<sub>6</sub>H<sub>5</sub>)3*C<sub>5</sub>H<sub>5</sub><sup>(1-)</sup> = Au(P(C<sub>6</sub>H<sub>5</sub>)3)(C<sub>5</sub>H<sub>5</sub>)

Synonyms:Au⁽¹⁺⁾*P(C₆H₅)3*C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅)

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Chemical Property of Au⁽¹⁺⁾*P(C₆H₅)3*C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅) Edit

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Technology Process of Au⁽¹⁺⁾*P(C₆H₅)3*C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅)

There total 3 articles about Au⁽¹⁺⁾*P(C₆H₅)3*C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 53317-87-6
tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate

: 7646-69-7
sodium hydride

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 21135-20-6
cyclopentadienyl(triphenylphosphine)gold

Guidance literature:: In tetrahydrofuran; (Ar), a susp. of BF4-salt, NaH and C5H6 in THF stirred at 0°C for 15 min, soln. diluted with petroleum ether cooled to 0°C, filtered, poured in ice water with stirring; separated, washed with cold ethanol and ether, dried in vac.;

Reference yield: 76.0%

: 14243-64-2
(triphenylphosphine)gold(I) chloride

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 21135-20-6
Au⁽¹⁺⁾*P(C₆H₅)3*C₅H₅^(1-) = Au(P(C₆H₅)3)(C₅H₅)

Guidance literature:: With Na(OC₂H₅); In ethanol; byproducts: NaCl, C2H5OH; sodium ethoxide and cyclopentadiene added to a suspn. of Au-compound; stirred overnight; IR, NMR;
DOI:10.1039/DT9860000411

Reference yield: 61.0%

: 79384-10-4,14243-65-3
bromo(triphenylphosphine)gold(I)

: sodium cyclopentadienide

: 21135-20-6
cyclopentadienyl(triphenylphosphine)gold

Guidance literature:: In tetrahydrofuran; to a soln. of AuBrPPh3 in THF added soln. of NaC5H5 in THF at -35°C, after 40 min mixture heated to 0°C, poured into ice water with stirring; filtered, washed with water and cold acetone, dissolved in 4:1 acetone-THF mixture cooled to 0°C, ice water added;