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TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE is a complex chemical compound with the formula [(C6H5)3PAu]+[BF4]-. It is a gold(I) complex that features a gold atom coordinated to three triphenylphosphine ligands, forming a stable, neutral complex. The tetrafluoroborate anion, [BF4]-, balances the charge of the complex. TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE is of interest in organometallic chemistry and is used in various applications, including as a catalyst in organic synthesis and in the study of gold chemistry. It is known for its stability and unique electronic properties, which make it a valuable tool in the development of new chemical reactions and materials.

53317-87-6

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53317-87-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 53317-87-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,3,3,1 and 7 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 53317-87:
(7*5)+(6*3)+(5*3)+(4*1)+(3*7)+(2*8)+(1*7)=116
116 % 10 = 6
So 53317-87-6 is a valid CAS Registry Number.
InChI:InChI=1/3C18H15P.3Au.BF4.O/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;2-1(3,4)5;/h3*1-15H;;;;;/q;;;;;;-1;+1/r3C18H15P.Au3O.BF4/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-4(2)3;2-1(3,4)5/h3*1-15H;;/q;;;+1;-1

53317-87-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name oxidanium,gold,triphenylphosphane,tetrafluoroborate

1.2 Other means of identification

Product number -
Other names [(PPh3Au)3O]BF4

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:53317-87-6 SDS

53317-87-6Relevant academic research and scientific papers

NEW ORGANOGOLD COMPLEXES: TETRAPHENYLCYCLOPENTADIENE DERIVATIVES

Perevalova, E. G.,Grandberg, K. I.,Dyadchenko, V. P.,Baukova, T. V.

, p. 403 - 413 (2007/10/02)

Mono- and diaurated derivatives of tetraphenylcyclopentadiene, Ph4C5HAuPPh3 and Ph4C5(AuPPh3)2, have been obtained by auration of tetraphenylcyclopentadiene with tris(triphenylphophinegold)oxonium tetrafluoroborate.Under the action of +BF4- both mono- and diaurated derivatives form the trinuclear cationic complex +BF4-, which is converted into Ph4C5(AuPPh3)2 when treated with nucleophiles.The structure of Ph4C5HAuPPh3 and +BF4- was established by IR, UV, PMR spectral and X-ray structural studies.Ph4C5HAuPPh3 has a C-Au bond and additional coordination of Au with two neighboring carbon atoms of the five-membered ring; the structure is non-fluxional.The complex +BF4- includes rather rare structural moieties: a three-membered carbometal cycle , three gold atoms linked to each other, Au-Au-Au, and univalent gold coordinated with three carbon atoms of the Ph4C5 ring.

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