(S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

Base Information

Chemical Name:(S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate
CAS No.:1347738-45-7
Molecular Formula:C₃₀H₃₈O₄Si
Molecular Weight:490.715
Hs Code.:

Synonyms:(S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

Chemical Property:

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Technology Process of (S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

There total 6 articles about (S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1347738-51-5
(S)-3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoic acid

: 18107-18-1
diazomethyl-trimethyl-silane

: 1347738-45-7
(S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

Guidance literature:: With methanol; In tetrahydrofuran; diethyl ether; at 20 ℃; for 1h;
DOI:10.1021/jo201988m

Reference yield:

: 1347738-32-2
(R)-3-((S)-3-((benzyloxy)methyl)hex-5-enoyl)-4-phenyl-1,3-oxazolidin-2-one

: 1347738-45-7
(S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

Guidance literature:: Multi-step reaction with 6 steps

1.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 18 h / 20 °C

2.1: sodium periodate / water; acetone; tert-butyl alcohol / 1 h / 20 °C

3.1: dimethylsulfide borane complex / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

4.1: 1H-imidazole; dmap / dichloromethane / 18 h / 20 °C / Inert atmosphere

5.1: dihydrogen peroxide; lithium hydroxide / tetrahydrofuran; water / 2 h / 20 °C

5.2: pH 4

6.1: methanol / tetrahydrofuran; diethyl ether / 1 h / 20 °C

With 1H-imidazole; methanol; dmap; sodium periodate; osmium(VIII) oxide; dimethylsulfide borane complex; water; dihydrogen peroxide; 4-methylmorpholine N-oxide; lithium hydroxide; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetone; tert-butyl alcohol;
DOI:10.1021/jo201988m

Reference yield:

: C₂₃H₂₇NO₆

: 1347738-45-7
(S)-methyl 3-((benzyloxy)methyl)-5-((tert-butyldiphenylsilyl)oxy)pentanoate

Guidance literature:: Multi-step reaction with 5 steps

1.1: sodium periodate / water; acetone; tert-butyl alcohol / 1 h / 20 °C

2.1: dimethylsulfide borane complex / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

3.1: 1H-imidazole; dmap / dichloromethane / 18 h / 20 °C / Inert atmosphere

4.1: dihydrogen peroxide; lithium hydroxide / tetrahydrofuran; water / 2 h / 20 °C

4.2: pH 4

5.1: methanol / tetrahydrofuran; diethyl ether / 1 h / 20 °C

With 1H-imidazole; methanol; dmap; sodium periodate; dimethylsulfide borane complex; dihydrogen peroxide; lithium hydroxide; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetone; tert-butyl alcohol;
DOI:10.1021/jo201988m