[2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

Base Information

Chemical Name:[2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide
CAS No.:85442-93-9
Molecular Formula:C₂₃H₄₀NO₈Si*I
Molecular Weight:613.562
Hs Code.:

Synonyms:[2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

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Chemical Property of [2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

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Technology Process of [2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

There total 4 articles about [2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6773-29-1
dimethyl diazomalonate

: 85442-93-9
[2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

Guidance literature:: Multi-step reaction with 2 steps

1: rhodium acetate / benzene / 60 °C

2: 1.) (C₂H₅)3N / 1.) CH₂Cl₂

With rhodium(II) acetate; triethylamine; In benzene;
DOI:10.1021/ja00348a070

Reference yield:

: 85442-91-7
(5R,6R)-5-Hydroxy-6-triethylsilanyloxy-cyclohexa-1,3-dienecarboxylic acid methyl ester

: 85442-93-9
[2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

Guidance literature:: Multi-step reaction with 2 steps

1: rhodium acetate / benzene / 60 °C

2: 1.) (C₂H₅)3N / 1.) CH₂Cl₂

With rhodium(II) acetate; triethylamine; In benzene;
DOI:10.1021/ja00348a070

Reference yield:

: 85442-90-6
(1R,2R,6R)-2-Triethylsilanyloxy-7-oxa-bicyclo[4.1.0]hept-3-ene-3-carboxylic acid methyl ester

: 85442-93-9
[2,2-Bis-methoxycarbonyl-2-((1R,6R)-5-methoxycarbonyl-6-triethylsilanyloxy-cyclohexa-2,4-dienyloxy)-ethyl]-trimethyl-ammonium; iodide

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / 1,8-diazabicyclo<5.4.0>undec-7-ene / diethyl ether; methanol / Ambient temperature

2: rhodium acetate / benzene / 60 °C

3: 1.) (C₂H₅)3N / 1.) CH₂Cl₂

With rhodium(II) acetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In methanol; diethyl ether; benzene;
DOI:10.1021/ja00348a070