Ru(η5-C60Me5)Cl(CO)2*toluene

Base Information

Chemical Name:Ru(η5-C60Me5)Cl(CO)2*toluene
CAS No.:557099-89-5
Molecular Formula:C₇H₈*C₆₇H₁₅ClO₂Ru
Molecular Weight:1080.52
Hs Code.:

Synonyms:Ru(η5-C60Me5)Cl(CO)2*toluene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ru(η5-C60Me5)Cl(CO)2*toluene

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Technology Process of Ru(η5-C60Me5)Cl(CO)2*toluene

There total 1 articles about Ru(η5-C60Me5)Cl(CO)2*toluene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: tricarbonyldichlororuthenium (II) dimer

: 108-88-3,15644-74-3,16713-13-6
toluene

: 244229-54-7
6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro-(C₆₀-Ih)[5,6]fullerene

: 557099-89-5
Ru(η5-C60Me5)Cl(CO)2*toluene

Guidance literature:: With t-BuOK; In tetrahydrofuran; under inert atm. to soln. C60Me5H in THF was added soln. t-BuOK in THF at 25°C and stirred for 15 min, (RuCl2(CO)3)2 was added and stirred for 30 min at 25°C; react. mixt. was passed through silica pad, product was purified by HPLC(toluene-isopropanol 7:3); elem. anal.;
DOI:10.1021/om0302387

Reference yield: 96.0%

: 557099-89-5
Ru(η5-C60Me5)Cl(CO)2*toluene

: 554-70-1
triethylphosphine

: 557099-91-9
Ru(η5-C60Me5)Cl(PEt3)(CO)*toluene

Guidance literature:: In toluene; under inert atm. to soln. Ru(η5-C60Me5)Cl(CO)2 in toluene was added soln. PEt3 in toluene and stirred and heated at 70°C for 12 h; react. mixt. was passed through silica pad, product was purified by HPLC; elem. anal.;
DOI:10.1021/om0302387

Reference yield: 93.0%

: 6738-06-3
phenylethynylmagnesium bromide

: 557099-89-5
Ru(η5-C60Me5)Cl(CO)2*toluene

: 557099-83-9
Ru(η5-C60Me5)(CCPh)(CO)2

Guidance literature:: In tetrahydrofuran; under inert atm. to soln. Ru(η5-C60Me5)Cl(CO)2 in THF at 25°Csoln. PhCCMgBr in THF was added and stirred at 25°C for 10 min; solvent was removed, residue was extd. with toluene, product was purified by HPLC (toluene-isopropanol 7:3); elem. anal.;
DOI:10.1021/om0302387