(1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

Base Information

Chemical Name:(1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside
CAS No.:767340-76-1
Molecular Formula:C₃₈H₅₄O₆Si₂
Molecular Weight:663.014
Hs Code.:

Synonyms:(1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

There total 7 articles about (1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: (E)-1-(Chloro-diethyl-silanyl)-3-trimethylsilanyl-propene

: 20672-67-7
methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside

: 767340-76-1
(1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1021/jo049061w

Reference yield:

: 767340-68-1
methyl 2-O-allyl(dimethyl)silanyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside

: 767340-76-1
(1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: TMSOTf; 2,6-DTBMP / acetonitrile / 14 h / 20 °C

2: 80 percent / imidazole; DMAP / CH₂Cl₂ / 24 h / 20 °C

With 1H-imidazole; dmap; trimethylsilyl trifluoromethanesulfonate; 2,6-di-tert-butyl-4-methyl-phenol; In dichloromethane; acetonitrile;
DOI:10.1021/jo049061w

Reference yield:

: 20672-69-9
methyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside

: 767340-76-1
(1'E)-methyl 3,4,6-tri-O-benzyl-2-O-[diethyl-(3'-trimethylsilanyl)prop-1'-enyl]silanyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / K₂CO₃ / methanol / 1 h / 20 °C

2: 80 percent / imidazole; DMAP / CH₂Cl₂ / 24 h / 20 °C

With 1H-imidazole; dmap; potassium carbonate; In methanol; dichloromethane;
DOI:10.1021/jo049061w