20672-67-7

Basic information

• Product Name: methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside
• Synonyms: methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside
• CAS NO: 20672-67-7
• Molecular Weight: 464.558
• Mol File: 20672-67-7.mol
• Article Data: 38

Chemical Properties

• CAS DataBase Reference: methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside(20672-67-7)
• EPA Substance Registry System: methyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside(20672-67-7)

Safety Data

• Hazardous Substances Data: 20672-67-7(Hazardous Substances Data)

Upstream product

• 97275-50-8 (E)-(2R,3R,4R)-6-methoxy-1,3,4-tribenzyloxy-5-hexen-2-ol 
• 100-44-7 benzyl chloride 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 104652-38-2 methyl 3,4,6-tri-O-benzyl-2-O-benzylsulfonyl-α-D-mannopyranoside 
• 67-56-1 methanol 
• 178931-69-6 Acetic acid (2R,3S,4S,5R,6R)-3,5-bis-benzyloxy-2-((2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-ethylsulfanyl-tetrahydro-pyran-3-yloxy)-6-methyl-tetrahydro-pyran-4-yl ester 
• 203176-75-4 Phenoxy-acetic acid (2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-3-yl ester 
• 301645-84-1 phenyl 2-O-(1-benzyloxy-2-iodopropyl)-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 20672-66-6 3,4,6-tri-O-benzyl-D-mannopyranose 
• 146864-77-9 3,4,6-tri-O-benzyl-1,2-O-(exo-methoxyethylidene)-β-D-mannopyranose 
• 1011723-04-8 glucal epoxide 
• 97204-75-6 (Z)-(2R,3R,4R)-6-methoxy-1,3,4-tribenzyloxy-5-hexen-2-ol 
• 20672-66-6 3,4,6-tri-O-benzyl-D-glucopyranose 

Downstream Products

• 80596-06-1 methyl O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 80596-05-0 methyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1<*>2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 87424-13-3 Acetic acid (2R,3R,4S,5S,6S)-3,4,5-tris-benzyloxy-6-((2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester 
• 87424-14-4 Acetic acid (2R,3R,4S,5S,6R)-3,4,5-tris-benzyloxy-6-((2S,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-methoxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-ylmethyl ester 
• 89912-37-8 Methyl-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-O-(3,6-di-O-acetyl-2-desoxy-2-phthalimido-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranosid 
• 131221-98-2 methyl O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-O-(3,6-di-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 81645-00-3 3,4,6-tri-O-benzyl-2-O-(3,4-di-O-benzyl-2-O-methylsulfonyl-β-L-rhamnopyranosyl)-α-D-mannopyranoside 
• 81656-55-5 3,4,6-tri-O-benzyl-2-O-(3,4-di-O-benzyl-2-O-methylsulfonyl-α-L-rhamnopyranosyl)-α-D-mannopyranoside 
• 138566-33-3 C₆₂H₆₂O₁₃ 
• 77770-57-1 methyl 3,4,6-tri-O-benzyl-2-bromo-2-deoxy-α-D-glucopyranoside 
• 73407-50-8 methyl 3,4,6-tri-O-benzyl-2-deoxy-2-iodo-α-D-glucopyranoside 
• 104639-38-5 3,4,6-tri-O-benzyl-2-O-methyl-β-D-glucopyranosyl fluoride 
• 104639-37-4 3,4,6-tri-O-benzyl-2-O-methyl-α-D-glucopyranosyl fluoride 
• 81644-97-5 3,4,6-tri-O-benzyl-2-O-(3,4-di-O-benzyl-2-O-methylsulfonyl-β-L-rhamnopyranosyl)-α-D-glucopyranoside 

Relevant articles and documents

A facile synthesis of neosaccharides: 2,6′-and 3,6′-ether- linked sugars

A novel synthesis of the 2,6′-O-linkage of methyl α-D-glucoside and methyl α-D-mannoside was developed based on an acetalization- reduction approach. Utilizing this approach, the 3,6′-O-linkage of methyl α-D-glucosides was also obtained. It is noteworthy

Arylboronic acid-mediated glycosylation of 1,2-dihydroxyglucoses

- We explored direct dehydrative coupling of tetrahydro-2H-pyran-2,3-diol or a 1,2-dihydroxy sugar with various alcohols using a range of arylboronic acids. Among the catalysts, 2-borono-4-trifluoromethylbenzoic acid efficiently promoted acetalization of tetrahydro-2H-pyran-2,3-diol. Ferroceniumboronic acid showed the best catalytic activity for glycosylation of the 1,2-dihydroxy sugar. The major products were 1,2-cJi-a-D-glucopyranosides.

A concise synthesis of single components of partially sulfated oligomannans

A concise synthesis of single components of C2 sulfated oligomannans including trimers, tetramers, and pentamers is reported. The synthesis features the application of the DMF-modulation method for the participatory thiomannoside donors in 1,2-trans α-glycosidic bond formation. The obtained oligomannans were fully characterized using 1H, 13C, COSY, and HSQC NMR spectroscopy.

Synthesis of the repeating trisaccharide unit of the cell wall lipopolysaccharide of Escherichia coli type 8

NIS/TfOH mediated glycosidation of methyl 3,4,6-tri-O-benzyl-α-d-mannopyranoside with phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-d-mannopyranoside furnished the corresponding disaccharide derivative in excellent yield and α-selectivity. Ze?mplen deacet