α,α-dimethylphenacylthiol

Base Information

• Chemical Name: α,α-dimethylphenacylthiol
• CAS No.: 14225-56-0
• Molecular Formula: C₁₀H₁₂OS
• Molecular Weight: 180.271
• Mol file: 14225-56-0.mol

Synonyms:α,α-dimethylphenacylthiol

Chemical Property of α,α-dimethylphenacylthiol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α,α-dimethylphenacylthiol

There total 3 articles about α,α-dimethylphenacylthiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

α-chloroisobutyrophenone (7473-99-6) → α,α-dimethylphenacylthiol (14225-56-0)

Guidance literature:

With sodium hydrogensulfide; In methanol; diethyl ether; at -20 ℃; for 4h;

DOI:10.1007/BF00808632

Reference yield: 78.0%

2-bromo-2-methyl-1-phenyl-propan-1-one (10409-54-8) → α,α-dimethylphenacylthiol (14225-56-0)

Guidance literature:

With trisodium thiophosphate; In N,N-dimethyl-formamide; for 5h;

DOI:10.1016/S0040-4039(00)77459-4

Reference yield:

2-isopropyl-5,5-dimethyl-2,4-diphenyl-2,5-dihydro-thiazole (14225-53-7) → α,α-dimethylphenacylthiol (14225-56-0)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane;

DOI:10.1007/BF00902605

upstream raw materials:

2-bromo-2-methyl-1-phenyl-propan-1-one

α-chloroisobutyrophenone

2-isopropyl-5,5-dimethyl-2,4-diphenyl-2,5-dihydro-thiazole

Downstream raw materials:

S-α,α-dimethylphenacyl thioacetate

Bis-<1-phenyl-isobutanon-(1)-yl-(2)>-trisulfid

phenyl isopropyl ketone

2-ethyl-2,5,5-trimethyl-4-phenyl-2,5-dihydro-thiazole

Refernces

• 1、 Hornbuckle, S. F.,Livant, P.,Webb, T. R.. "Sulfuranes with Oximate Axial Ligands". . p. 4153 - 4159. Retrieved 2007/10/02.
• 2、 Asinger, Friedrich,Schmitz, Maria Karoline. "On the Joint Reaction of Elemental Selenium with Gaseous Ammonia and Ethylenimine, respectively in the Presence of Ketones. Joint Reaction of Elementary Sulfur and Gaseous Ammonia with Ketones, 96.". . p. 1191 - 1212. Retrieved 2007/10/02.