(S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

Base Information

Chemical Name:(S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine
CAS No.:206191-82-4
Molecular Formula:C₂₁H₃₁NO₂S
Molecular Weight:361.549
Hs Code.:

Synonyms:(S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

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Technology Process of (S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

There total 3 articles about (S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 33993-53-2
N,S-dimethyl-S-phenylsulfoximine

: 16643-72-4,18679-63-5,18679-65-7,65648-16-0,65648-17-1
trans-3-isopropyl-7a-methyl-1,2,3,6,7,7a-hexahydroinden-5-one

: 206191-82-4
(S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

: 206191-83-5
C₂₁H₃₁NO₂S

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.333333h;
DOI:10.1055/s-1998-5921

Reference yield:

: 106-72-9
2,6-dimethyl-5-hepten-1-al

: 206191-82-4
(S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

Guidance literature:: Multi-step reaction with 3 steps

2: 73 percent / EtAlCl₂ / CH₂Cl₂; hexane / 4 h / Ambient temperature

3: 34 percent / BuLi / tetrahydrofuran; hexane / 0.33 h / -78 °C

With n-butyllithium; ethylaluminum dichloride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1055/s-1998-5921

Reference yield:

: 75265-33-7
4-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-2-en-1-one

: 206191-82-4
(S)-N-Methyl-S-phenyl-S-{[(3S,5R,7aR)-5,6,7,7a-tetrahydro-5-hydroxy-3-isopropyl-7a-methyl-5-indanyl]methyl}sulfoximine

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / EtAlCl₂ / CH₂Cl₂; hexane / 4 h / Ambient temperature

2: 34 percent / BuLi / tetrahydrofuran; hexane / 0.33 h / -78 °C

With n-butyllithium; ethylaluminum dichloride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1055/s-1998-5921