Cs{7-(CH₃)-8(C₆H₅)-7,8-C₂B₉H₁₀}

Base Information

• Chemical Name: Cs{7-(CH₃)-8(C₆H₅)-7,8-C₂B₉H₁₀}
• CAS No.: 89486-20-4
• Molecular Formula: C₉H₁₈B₉*Cs
• Molecular Weight: 356.446
• Mol file: 89486-20-4.mol

Synonyms:Cs{7-(CH₃)-8(C₆H₅)-7,8-C₂B₉H₁₀}

Chemical Property of Cs{7-(CH₃)-8(C₆H₅)-7,8-C₂B₉H₁₀}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cs{7-(CH₃)-8(C₆H₅)-7,8-C₂B₉H₁₀}

There total 4 articles about Cs{7-(CH₃)-8(C₆H₅)-7,8-C₂B₉H₁₀} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cesium dodecahydrodicarba-nido-undecaborate (63748-65-2) + [exo-nido-(PPh3)2Rh(7-Me-8-Ph-7,8-C2B9H10)] (89397-42-2) → Cs[nido-7-Me-8-Ph-7,8-C2B9H10] (89486-20-4) + closo-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11 (53687-46-0)

Guidance literature:

With Cs(7,9-C₂B₉H₁₂); In tetrahydrofuran; benzene-d6; under Ar, THF soln. of carboranes added to THF/C6D6 soln. of Rh complexat -78°C, equilibrated at -63°C; monitored by NMR; Kinetics;

DOI:10.1021/ja00322a041

Reference yield:

[exo-nido-(PPh3)2Rh(7-Me-8-Ph-7,8-C2B9H10)] (89397-42-2) + Cs[nido-2,9-C2B9H12] (89486-21-5) → Cs[nido-7-Me-8-Ph-7,8-C2B9H10] (89486-20-4) + {closo-2,2-(PPh3)2-2-H-2,1,12-RhC2B9H11} (76287-18-8)

Guidance literature:

With Cs(7,9-C₂B₉H₁₂); In tetrahydrofuran; benzene-d6; under Ar, THF soln. of carboranes added to THF/C6D6 soln. of Rh complexat -78°C, equilibrated at -63°C; monitored by NMR; Kinetics;

DOI:10.1021/ja00322a041

Reference yield:

[exo-nido-(PPh3)2Rh(7-Me-8-Ph-7,8-C2B9H10)] (89397-42-2) + Cs[nido-7,9-C2B9H12] (12305-33-8) → Cs[nido-7-Me-8-Ph-7,8-C2B9H10] (89486-20-4) + closo-2,2-(PPh3)2-2-H-2,1,7-RhC2B9H11 (53754-45-3)

Guidance literature:

In tetrahydrofuran; benzene-d6; under Ar, THF soln. of carborane added to THF/C6D6 soln. of Rh complex at -78°C, equilibrated at -63°C; monitored by NMR;

DOI:10.1021/ja00322a041

upstream raw materials:

cesium dodecahydrodicarba-nido-undecaborate

[exo-nido-(PPh₃)2Rh(7-Me-8-Ph-7,8-C₂B₉H₁₀)]

Cs[nido-7,9-C₂B₉H₁₂]

Cs[μ-7,8-trimethylene-7,8-C2B9H10]

Downstream raw materials:

{closo-1-(CH₃)-8-(C₆H₅)-1,8-C₂B₉H₉

[exo-nido-(PPh₃)2Rh(7-Me-8-Ph-7,8-C₂B₉H₁₀)]

Cs[μ-7,8-trimethylene-7,8-C2B9H10]