Cs[μ-7,8-trimethylene-7,8-C2B9H10]

Base Information

Chemical Name:Cs[μ-7,8-trimethylene-7,8-C2B9H10]
CAS No.:89462-13-5
Molecular Formula:C₅H₁₆B₉*Cs
Molecular Weight:306.386
Hs Code.:

Synonyms:Cs[μ-7,8-trimethylene-7,8-C2B9H10]

Suppliers and Price of Cs[μ-7,8-trimethylene-7,8-C2B9H10]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cs[μ-7,8-trimethylene-7,8-C2B9H10]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cs[μ-7,8-trimethylene-7,8-C2B9H10]

There total 2 articles about Cs[μ-7,8-trimethylene-7,8-C2B9H10] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 23940-20-7
μ-1,2-trimethylene-o-carborane

: 13400-13-0
cesium fluoride

: 89462-13-5
Cs[μ-7,8-trimethylene-7,8-C2B9H10]

: 7637-07-2
boron trifluoride

: 13842-55-2
boron difluoride

Guidance literature:: In ethanol; under N2; mixt. of B compd. and CsF (molar ratio 1:3) in EtOH stirred under reflux for 25 h; cooled to room temp.; dried in vac. by rotary evaporator; dissolved in acetone; filtered by glass frit; washed with acetone; solvent removed from filtrate in vac.; recrystd. from H2O; elem. anal.;
DOI:10.1021/ic000768k

Reference yield:

: 89486-20-4
Cs[nido-7-Me-8-Ph-7,8-C₂B₉H₁₀]

: 127916-00-1
exo-nido-(PPh3)2Rh-7,8-(μ-(CH2)3)-7,8-C2B9H10

: 89397-42-2
[exo-nido-(PPh₃)2Rh(7-Me-8-Ph-7,8-C₂B₉H₁₀)]

: 89462-13-5
Cs[μ-7,8-trimethylene-7,8-C2B9H10]

Guidance literature:: In tetrahydrofuran; benzene-d6; under Ar, THF soln. of carborane added to THF/C6D6 soln. of Rh complex at -78°C, equilibrated at -33°C; monitored by NMR;
DOI:10.1021/ja00322a041

Reference yield: 81.0%

: 14694-95-2
tris(triphenylphosphine)rhodium(l) chloride

: 89462-13-5
Cs[μ-7,8-trimethylene-7,8-C2B9H10]

: 89437-71-8
[exo-nido-(PPh3)2Rh(7,8-μ-(CH2)3-7,8-C2B9H10)]*benzene

Guidance literature:: With benezene; In ethanol; benzene; under N2 or Ar, soln. of reagents in benzene/ethanol stirred at room temp. for 24 h, gently refluxed for 2.5 h, allowed to cool to room temp.; filtered, ethanol added, concd. in vac., ppt. collected by filtration, washed with ethanol, dried in vac.; elem. anal.;
DOI:10.1021/ja00322a039