4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

Base Information

Chemical Name:4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)
CAS No.:1642593-98-3
Molecular Formula:C₁₆H₈Cl₂F₆
Molecular Weight:385.136
Hs Code.:

Synonyms:4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

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Chemical Property of 4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

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Technology Process of 4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

There total 3 articles about 4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 2642-81-1
1,1-bis(p-chlorophenyl)ethene

: Umemoto's reagent

: 1642593-98-3
4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

: 4,4′-(3,3,3-trifluoroprop-1-ene-1,1-diyl)bis(chlorobenzene)

Guidance literature:: With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; In dimethyl sulfoxide; at 20 ℃; for 2h; Schlenk technique; Inert atmosphere; Irradiation;
DOI:10.3762/bjoc.10.108

Reference yield: 41.0%

: 1540-63-2
4,4'-(2,2-difluoroethene-1,1-diyl)bis(chlorobenzene)

: 81290-20-2
(trifluoromethyl)trimethylsilane

: 1642593-98-3
4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 30 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2015.08.016

Reference yield:

: 90-98-2
4,4'-Dichlorobenzophenone

: 1642593-98-3
4,4'-(3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene-1,1-diyl)bis(chlorobenzene)

: 4,4′-(3,3,3-trifluoroprop-1-ene-1,1-diyl)bis(chlorobenzene)

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hexamethyldisilazane / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

1.2: 20 °C / Inert atmosphere

2.1: tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate / dimethyl sulfoxide / 2 h / 20 °C / Schlenk technique; Inert atmosphere; Irradiation

With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; sodium hexamethyldisilazane; In tetrahydrofuran; dimethyl sulfoxide; 1.1: |Wittig Olefination / 1.2: |Wittig Olefination;
DOI:10.3762/bjoc.10.108