{bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2

Base Information

• Chemical Name: {bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2
• CAS No.: 118018-87-4
• Molecular Formula: C₃₂H₅₂N₆O₅Ru₂*2F₆P
• Molecular Weight: 1092.87
• Mol file: 118018-87-4.mol

Synonyms:{bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2

Chemical Property of {bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2

There total 2 articles about {bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

potassium hexafluorophosphate (17084-13-8) + C9H21Cl3N3Ru(2-)*H2O + benzoic acid (65-85-0,8013-63-6) → {bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2 (118018-87-4)

Guidance literature:

C₉H₂₁Cl₃N₃Ru^(2-)*H₂O; benzoic acid; In water; for 1h; Reflux;

potassium hexafluorophosphate; In water; at 20 ℃;

DOI:10.1016/j.ica.2021.120409

Reference yield:

sodium benzoate (532-32-1) + sodium hexaflorophosphate + {(1,4,7-trimethyl-1,4,7-triazacyclononane)RuCl3}*H2O (118018-83-0) → {bis(1,4,7-trimethyl-1,4,7-triazacyclononane)(μ-oxo)bis(μ-PhCOO)diruthenium(III)}(PF6)2 (118018-87-4)

Guidance literature:

In water; suspension of Ru salt in aq. soln. contg. sodium carboxylate (pH 7) was refluxed 30 min; addn. of aq. NaPF6 soln. to hot soln.; cooling to 0°C, 12h; crystals formed; elem. anal.;

upstream raw materials:

sodium benzoate

{(1,4,7-trimethyl-1,4,7-triazacyclononane)RuCl₃}*H₂O

potassium hexafluorophosphate

benzoic acid