(1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

Base Information

Chemical Name:(1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol
CAS No.:406160-49-4
Molecular Formula:C₁₅H₂₄O₃
Molecular Weight:252.354
Hs Code.:

Synonyms:(1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

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Chemical Property of (1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

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Technology Process of (1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

There total 2 articles about (1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 17678-70-5
Zerumbol

: 118-97-8
4-chloro-3,5-dinitrobenzoic acid

: (1R,2R,3R)-2,3-epoxy-2,6,9,9-tetramethyl-6,10-cycloundecadienyl 4-chloro-3,5-dinitrobenzoate

: (1S,2S,3S)-2,3-epoxy-2,6,9,9-tetramethyl-6,10-cycloundecadienyl 4-chloro-3,5-dinitrobenzoate

: 406160-49-4
(1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

Guidance literature:: Zerumbol; With titanium(IV) isopropylate; diethyl (2R,3R)-tartrate; di-tert-butyl peroxide; In dichloromethane; at -30 - -26 ℃; for 48h;

4-chloro-3,5-dinitrobenzoic acid; With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃; for 3h; Title compound not separated from byproducts;
DOI:10.1016/j.tetasy.2006.06.049

Reference yield: 40.0%

: 17678-70-5
Zerumbol

: 118-97-8
4-chloro-3,5-dinitrobenzoic acid

: (1R,2R,3R)-2,3-epoxy-2,6,9,9-tetramethyl-6,10-cycloundecadienyl 4-chloro-3,5-dinitrobenzoate

: (1S,2S,3S)-2,3-epoxy-2,6,9,9-tetramethyl-6,10-cycloundecadienyl 4-chloro-3,5-dinitrobenzoate

: (1SR,2SR,3SR)-2,3-epoxy-2,6,9,9-tetramethyl-6,10-cycloundecadienyl 4-chloro-3,5-dinitrobenzoate

: 406160-49-4
(1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

Guidance literature:: Zerumbol; With titanium(IV) isopropylate; diethyl (2R,3R)-tartrate; di-tert-butyl peroxide; In dichloromethane; at -30 - -26 ℃; for 48h;

4-chloro-3,5-dinitrobenzoic acid; With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃; for 3h;

In ethanol;
DOI:10.1016/j.tetasy.2006.06.049

Reference yield: 46.0%

: 122-01-0
4-chloro-benzoyl chloride

: 406160-49-4
(1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol

: (1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecenyl p-chlorobenzoate

Guidance literature:: (1R,2S,3R,10S,11R)-2,3-10,11-diepoxy-2,6,9,9-tetramethyl-6-cycloundecen-1-ol; With sodium hydride; In diethyl ether; at 20 ℃; for 0.166667h;

4-chloro-benzoyl chloride; In diethyl ether; for 18h;
DOI:10.1016/S0957-4166(01)00505-5