(S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

Base Information

Chemical Name:(S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene
CAS No.:1083071-89-9
Molecular Formula:C₄₅H₅₀FeP₂
Molecular Weight:708.687
Hs Code.:

Synonyms:(S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

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Chemical Property of (S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

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Technology Process of (S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

There total 1 articles about (S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 859839-98-8
(S(Fc),R(P))-2-(1-naphthylphenylphosphanyl)ferrocenecarboxaldehyde

: 83115-12-2
(2,4,6-tri-tert-butylphenyl)phosphine

: 1083071-89-9
(S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

Guidance literature:: With n-C₄H₉Li; (CH₃)3SiCl; In tetrahydrofuran; hexane; (N2); using Schlenk techniques; addn. of BuLi/hexane to PH2C6H2(t-Bu)3/THF at -78°C; stirring for 15 min+0.5 h at r.t.; addn. of Me3SiCl and after 0.5 h BuLi/hexane; stirring for 0.5h; cooling; addn. of CpFeC5H3CHOPPh(C10H7)/THF; stirring at r.t.; addn. of Me3SiCl; stirring for 15 min; concn. to dryness under vac., flash chromy. (SiO2, hexane/CH2Cl2 = 90/10); elem. anal.;
DOI:10.1021/om8008316

Reference yield: 87.0%

: bis(η3-allyl-μ-chloropalladium(II))

: 1083071-89-9
(S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

: 2923-28-6
silver trifluoromethanesulfonate

: [Pd(η3-allyl)((S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene)]OTf

Guidance literature:: In dichloromethane; byproducts: AgCl; (N2); using Schlenk techniques; dissolving of (Pd(η3-allyl)(μ-Cl))2 and CpFe(C5H3(CHPC6H2(t-Bu)3)PPh(1-naphthyl)) in CH2Cl2 at room temp.; cooling to 0°C; addn. of AgOTf; stirring at room temp. for 2 h; pptn., filtration, concn. to dryness; washing with hexane; drying under vac.; as mixt. of endo and exo isomers; elem. anal.;
DOI:10.1021/om8008316

Reference yield:

: bis[dimethyl(μ-dimethylsulfide)platinum(II)]

: 60-29-7,927820-24-4
diethyl ether

: 1083071-89-9
(S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene

: 1083072-02-9
[((S)-1-CHP(2,4,6-tri-t-butylphenyl)-2-(1-naphthylphenylphosphanyl)ferrocene)PtMe₂]*C₄H₁₀O

Guidance literature:: In diethyl ether; (N2); using Schlenk techniques; addn. of CpFe(C5H3(CHPC6H2(t-Bu)3)(PPh(1-naphthyl))) to suspn. of (PtMe2(SMe2))2 in Et2O; stirring at room temp.overnight; removal of volatile materials under reduced pressure, dissolving in min.amt. of CH2Cl2; layering with pentane; crystn. at 0°C; recrystn. from Et2O; elem. anal.;
DOI:10.1021/om8008316