(2,2'-Bipyridine)nickel(II) dibromide

Base Information

• Chemical Name: (2,2'-Bipyridine)nickel(II) dibromide
• CAS No.: 46389-47-3
• Molecular Formula: C₁₀H₈Br₂N₂Ni
• Molecular Weight: 374.685
• DSSTox Substance ID: DTXSID201319296
• Mol file: 46389-47-3.mol

Synonyms:nibr2(bipy);46389-47-3;(2,2'-Bipyridine)nickel(II) dibromide;(2,2'-Bipyridine)nickel(II)dibromide;SCHEMBL196502;CYKXDHXBWOTQKY-UHFFFAOYSA-L;DTXSID201319296;dibromonickel;2-pyridin-2-ylpyridine;(2,2'-bipyridine) nickel(II)-dibromide;D80542

Chemical Property of (2,2'-Bipyridine)nickel(II) dibromide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 373.83872
• Heavy Atom Count: 15
• Complexity: 123

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.[Ni](Br)Br

Technology Process of (2,2'-Bipyridine)nickel(II) dibromide

There total 8 articles about (2,2'-Bipyridine)nickel(II) dibromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

1-bromocyclohexane (108-85-0) + (2,2'-dipyridyl)nickelacyclopropionate → (2,2'-bipyridine)nickel(II) dibromide (46389-47-3) + cyclohexanepropionic acid (701-97-3)

Guidance literature:

With manganese(II) bromide; hydrogen bromide; In N,N-dimethyl-formamide; room temp., 24 h;

Reference yield:

C6H5CH2Ni(bpy)Br → (2,2'-bipyridine)nickel(II) dibromide (46389-47-3) + nickel (7440-02-0)

Guidance literature:

In neat (no solvent); byproducts: C6H5CH2CH2C6H5, C5H4NC5H4N; decompn. on storing at room temp.;;

Reference yield:

2-bromothiophene (1003-09-4) + Ni(C10H8N2)(C7H7)Br → (2,2'-bipyridine)nickel(II) dibromide (46389-47-3) + Ni(C10H8N2)(C4H3S)(C7H7)(1+)*Br(1-)=Ni(C10H8N2)(C4H3S)(C7H7)Br

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In N,N-dimethyl-formamide; byproducts: 2-(o-tolyl)thiophene; Electrochem. Process; electrochemical reduction at -1.35 and -1.55 V; magnesium rod anode, Au working electrode; cyclovoltammetry;

upstream raw materials:

1-bromocyclohexane

diethyl(2,2'-bipyridyl)nickel(II)

benzyl bromide

2-bromothiophene

Downstream raw materials:

(2,2'-bipyridine)bis(mesityl)nickel

[NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)]

(2,2'-bipyridine)bromobis(2-tolyl)nickel

nickel