[NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)]

Base Information

• Chemical Name: [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)]
• CAS No.: 474353-55-4
• Molecular Formula: C₁₉H₁₉BrN₂Ni
• Molecular Weight: 413.967
• Mol file: 474353-55-4.mol

Synonyms:[NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)]

Chemical Property of [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)]

There total 3 articles about [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

[2,2]bipyridinyl (366-18-7) + bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 2,4,6-trimethylphenyl bromide (576-83-0) → [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)] (474353-55-4)

Guidance literature:

[2,2]bipyridinyl; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 24h;

2,4,6-trimethylphenyl bromide; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1021/jacs.1c05255

Reference yield: 85.0%

(2,2'-bipyridine)nickel(II) dibromide (46389-47-3) + 2,4,6-trimethylphenyl bromide (576-83-0) → [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)] (474353-55-4)

Guidance literature:

In N,N-dimethyl-formamide; Electrolysis; under Ar; electrolysis of a soln. of nickel complex and ligand in DMF at-1.52 V; addn. of water, extn. with ether, washing with water, drying, evapn.; elem. anal.;

DOI:10.1016/S0022-328X(01)00813-0

Reference yield:

(2,2'-bipyridine)nickel(II) dibromide (46389-47-3) + 2,4,6-trimethylphenyl bromide (576-83-0) → [NiBr(2,4,6-trimethylphenyl)(2,2'-bipyridine)] (474353-55-4)

Guidance literature:

With tetraethylammonium bromide; In N,N-dimethyl-formamide; Electrolysis; electrolysis of a soln. of nickel complex, ligand, Et4NBr in DMF at -1.52 V versus Ag/0.1 M AgNO3 in MeCN, passing 27 mA*h; evapn., extn. with ether, evapn., drying in vac. at 30°C; elem. anal.;

DOI:10.1023/A:1016024531639

upstream raw materials:

(2,2'-bipyridine)nickel(II) dibromide

2,4,6-trimethylphenyl bromide

(2,2'-bipyridine)nickel(II) dibromide

[2,2]bipyridinyl

Downstream raw materials:

Ni(mesityl)(NH=C(mesityl)(Ph))(2,2'-bipyridine)BF₄

Ni(mesityl)(NH=C(mesityl)(Me))(2,2'-bipyridine)BF₄

dimesityl phosphine

mesitylphosphine