N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine

Base Information

• Chemical Name: N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine
• CAS No.: 884050-44-6
• Molecular Formula: C₂₂H₂₆F₂N₂
• Molecular Weight: 356.459
• Mol file: 884050-44-6.mol

Synonyms:N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine

Chemical Property of N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine

There total 1 articles about N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1,2-bis(4-fluorophenyl)ethane-1,2-dione (579-39-5) + tert-butylamine (75-64-9) → N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine (884050-44-6)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at 0 - 20 ℃;

DOI:10.1002/anie.200502985

Reference yield: 72.0%

N,N'-bis(1,1-dimethylethyl)-1,2-bis(4-fluorophenyl)ethane-1,2-diimine (884050-44-6) + iron(dichloride)*1.5(tetrahydrofuran) → [(t)Bu-N=C(para-fluorophenyl)-C(para-fluorophenyl)=N-(t)Bu]FeCl2 (884050-46-8)

Guidance literature:

In dichloromethane; soln. stirred for 24 h; soln. filtered, solvent removed in vacuo; washed with pentane;

DOI:10.1002/anie.200502985

upstream raw materials:

1,2-bis(4-fluorophenyl)ethane-1,2-dione

tert-butylamine

Downstream raw materials:

[(t)Bu-N=C(para-fluorophenyl)-C(para-fluorophenyl)=N-(t)Bu]FeCl₂