{η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3

Base Information

• Chemical Name: {η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3
• CAS No.: 478612-90-7
• Molecular Formula: C₂₀H₂₇Cl₃SiTi
• Molecular Weight: 449.759
• Mol file: 478612-90-7.mol

Synonyms:{η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3

Chemical Property of {η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3

Chemical Property:

Purity/Quality:

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Technology Process of {η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3

There total 1 articles about {η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

C5H3(SiMe3)2C[(CH2)5]Ph (478612-93-0) + titanium tetrachloride (7550-45-0) → {η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3 (478612-90-7)

Guidance literature:

In dichloromethane; byproducts: Me3SiCl; under N2; to a soln. of TiCl4 (3.2 mmol) in CH2Cl2 at -40°C was added dropwise Si-contg. compd. (3.3 mmol); the mixt. was warmed to room temp. and stirred overnight; the volatiles were removed in vac.; the residue was stripped with pentane; extn. with CH2Cl2; elem. anal.;

DOI:10.1021/om020765a

Reference yield: 60.0%

triethanolamine (102-71-6,64114-46-1) + {η5-(3-SiMe3)C5H3C[(CH2)5]Ph}TiCl3 (478612-90-7) → [η5-(3-SiMe3)C5H3C[(CH2)5]Ph]Ti(TEA)

Guidance literature:

With triethylamine; In toluene; at -78 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1007/s11243-012-9607-2

upstream raw materials:

C₅H₃(SiMe₃)2C[(CH₂)5]Ph

titanium tetrachloride