2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

Base Information

Chemical Name:2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone
CAS No.:1384870-48-7
Molecular Formula:C₂₈H₄₀O₃Si₂
Molecular Weight:480.795
Hs Code.:

Synonyms:2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

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Chemical Property of 2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

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Technology Process of 2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

There total 5 articles about 2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 994-30-9
triethylsilyl chloride

: 1384870-71-6
C₂₂H₂₆O₃Si

: 1384870-48-7
2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 24h; Inert atmosphere; Reflux;
DOI:10.1021/ol301513h

Reference yield:

: 28921-35-9
2-methyl-3-ethoxycarbonyl-furan

: 1384870-48-7
2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

Guidance literature:: Multi-step reaction with 5 steps

1.1: lithium aluminium tetrahydride / diethyl ether / 1 h / 28 °C / Inert atmosphere

2.1: bromine / diethyl ether / 3 h / -78 °C

2.2: 1 h / -78 - 20 °C

3.1: hydroquinone / 3.5 h / pH 6.3 / aq. phosphate buffer; Reflux

4.1: 1H-imidazole; dmap / N,N-dimethyl-formamide / 0.17 h / Inert atmosphere

4.2: 0 - 20 °C / Inert atmosphere

5.1: dmap; triethylamine / dichloromethane / 24 h / Inert atmosphere; Reflux

With 1H-imidazole; dmap; lithium aluminium tetrahydride; bromine; triethylamine; hydroquinone; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol301513h

Reference yield:

: 76374-24-8,76374-33-9,90371-07-6
2,5-dihydro-3-hydroxymethyl-2,5-dimethoxy-2-methylfuran

: 1384870-48-7
2-(tert-butyldiphenylsilanyloxymethyl)-4-(triethylsilanyloxy)cyclopent-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1.1: hydroquinone / 3.5 h / pH 6.3 / aq. phosphate buffer; Reflux

2.1: 1H-imidazole; dmap / N,N-dimethyl-formamide / 0.17 h / Inert atmosphere

2.2: 0 - 20 °C / Inert atmosphere

3.1: dmap; triethylamine / dichloromethane / 24 h / Inert atmosphere; Reflux

With 1H-imidazole; dmap; triethylamine; hydroquinone; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol301513h