1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate

Base Information

• Chemical Name: 1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate
• CAS No.: 169872-54-2
• Molecular Formula: C₃₆H₃₇NO₆
• Molecular Weight: 579.693
• Mol file: 169872-54-2.mol

Synonyms:1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate

Chemical Property of 1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate

There total 2 articles about 1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-(benzyloxycarbonyl)imino-D-glycero-L-galacto-heptitol (856174-72-6) → 1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O(7),N-cyclic carbamate (169872-54-2)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃; for 1h;

DOI:10.1016/j.carres.2010.01.021

Reference yield: 71.0%

3,4,5,7-tetra-O-benzyl-6-[(benzyloxycarbonyl)amino]-1,2,6-trideoxy-D-galacto-hept-1-enitol → 1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O(7),N-cyclic carbamate (169872-54-2)

Guidance literature:

3,4,5,7-tetra-O-benzyl-6-[(benzyloxycarbonyl)amino]-1,2,6-trideoxy-D-galacto-hept-1-enitol; With mercury(II) trifluoroacetate; In tetrahydrofuran; at 20 ℃; for 48h;

With sodium hydrogencarbonate; In tetrahydrofuran; for 2h;

With iodine; In tetrahydrofuran; at 0 - 25 ℃; for 0.75h;

DOI:10.1016/S0968-0896(00)00343-6

Reference yield: 85.0%

1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O(7),N-cyclic carbamate (169872-54-2) → 3,4,5,7-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O(7),N-cyclic carbamate (1227700-64-2)

Guidance literature:

With water; potassium hydroxide; In methanol; at 80 ℃; for 20h;

DOI:10.1016/j.carres.2010.01.021

upstream raw materials:

1,3,4,5-tetra-O-benzyl-2,6-dideoxy-2,6-(benzyloxycarbonyl)imino-D-glycero-L-galacto-heptitol

Downstream raw materials:

3,4,5,7-tetra-O-benzyl-2,6-dideoxy-2,6-imino-D-glycero-D-galacto-heptitol O⁽⁷⁾,N-cyclic carbamate