(7-Chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

Base Information

Chemical Name:(7-Chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate
CAS No.:107617-98-1
Molecular Formula:C₁₆H₁₅ClO₅S
Molecular Weight:354.811
Hs Code.:
European Community (EC) Number:600-840-3
DSSTox Substance ID:DTXSID501135661

Synonyms:SCHEMBL1044755;NCHHORSKFAJFKD-UHFFFAOYSA-N;DTXSID501135661;(7-chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate;107617-98-1;1,4-Benzodioxin-2-methanol, 7-chloro-2,3-dihydro-, 2-(4-methylbenzenesulfonate)

Suppliers and Price of (7-Chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (7-Chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

Chemical Property:

Vapor Pressure:1.27E-09mmHg at 25°C
XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:354.0328724
Heavy Atom Count:23
Complexity:483

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2COC3=C(O2)C=C(C=C3)Cl

Technology Process of (7-Chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

There total 3 articles about (7-Chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2242-32-2
(7-chloro-2,3-dihydrobenzo[b][1,4]dioxin-2-yl)methanol

: 98-59-9
p-toluenesulfonyl chloride

: 107617-98-1
(7-chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 0.75h;

Reference yield:

: 635-93-8
5-chlorosalicyclaldehyde

: 107617-98-1
(7-chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / N,N-dimethyl-formamide / 1 h / 100 °C

2: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / Reflux

3: sodium hydroxide / water / 0.5 h / Reflux

4: dmap; triethylamine / dichloromethane / 0.75 h / 20 °C

With dmap; potassium carbonate; triethylamine; 3-chloro-benzenecarboperoxoic acid; sodium hydroxide; In dichloromethane; water; N,N-dimethyl-formamide;

Reference yield:

: 1193392-79-8
5-chloro-2-(oxiran-2-ylmethoxy)phenol

: 107617-98-1
(7-chloro-2,3-dihydro-1,4-benzodioxin-2-yl)methyl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide / water / 0.5 h / Reflux

2: dmap; triethylamine / dichloromethane / 0.75 h / 20 °C

With dmap; triethylamine; sodium hydroxide; In dichloromethane; water;