2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

Base Information

Chemical Name:2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether
CAS No.:1393581-15-1
Molecular Formula:C₂₆H₃₆OSi₂
Molecular Weight:420.742
Hs Code.:

Synonyms:2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

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Chemical Property of 2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

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Technology Process of 2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

There total 3 articles about 2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1393581-14-0
2-(3'-chloro-5'-methylidenecyclohex-3'-enyl)ethan-1-yl diphenylmethylsilyl ether

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 1393581-15-1
2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

Guidance literature:: With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In tetrahydrofuran; diethyl ether; for 12h; Reflux;
DOI:10.1016/j.tet.2012.05.084

Reference yield:

: C₈H₁₁ClO₂

: 1393581-15-1
2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

Guidance literature:: Multi-step reaction with 3 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 0.5 h / 20 °C

2.1: potassium 2-methylbutan-2-olate / benzene / 1 h / Reflux

2.2: 0.5 h / 20 °C

3.1: 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) / tetrahydrofuran; diethyl ether / 12 h / Reflux

With 1H-imidazole; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); potassium 2-methylbutan-2-olate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; benzene;
DOI:10.1016/j.tet.2012.05.084

Reference yield:

: 43152-25-6
C₈H₁₀O₄

: 1393581-15-1
2-[5'-methylidene-3'-(trimethylsilylmethyl)cyclohex-3'-enyl]ethan-1-yl diphenylmethylsilyl ether

Guidance literature:: Multi-step reaction with 5 steps

1.1: oxalyl dichloride / 0.5 h / Reflux

2.1: lithium tris[(3-ethyl-3-pentyl)oxy]aluminohydride / tetrahydrofuran / 4.5 h / -78 °C

2.2: -78 °C / Saturated solution

3.1: 1H-imidazole / N,N-dimethyl-formamide / 0.5 h / 20 °C

4.1: potassium 2-methylbutan-2-olate / benzene / 1 h / Reflux

4.2: 0.5 h / 20 °C

5.1: 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) / tetrahydrofuran; diethyl ether / 12 h / Reflux

With 1H-imidazole; oxalyl dichloride; lithium tris[(3-ethyl-3-pentyl)oxy]aluminohydride; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); potassium 2-methylbutan-2-olate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; benzene;
DOI:10.1016/j.tet.2012.05.084