4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

Base Information

Chemical Name:4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol
CAS No.:1257079-30-3
Molecular Formula:C₁₃H₅BrF₁₄O
Molecular Weight:523.064
Hs Code.:

Synonyms:4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

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Chemical Property of 4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

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Technology Process of 4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

There total 4 articles about 4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoro-4-phenylheptan-4-ol

: 1257079-30-3
4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

Guidance literature:: 1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoro-4-phenylheptan-4-ol; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In hexane; at 0 - 20 ℃; Inert atmosphere;

With 1,2-dibromo-1,1,2,2-tetrafluoroethane; In hexane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1039/c0dt00539h

Reference yield: 5.0%

: 1401324-94-4
2-[3,3-bis(1,1,2,2,3,3,3-heptafluoropropyl)-2,1-benzoxarsol-1(3H)-yl]-α,α-bis(1,1,2,2,3,3,3-heptafluoropropyl)benzenemethanol

: 594-19-4
tert.-butyl lithium

: 1257079-30-3
4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

: 1401324-95-5
C₂₆H₉AsF₂₈O₃

: 1401324-92-2,1401352-18-8
1-(1,1-dimethylethyl)-3,3,3',3'-tetrakis(1,1,2,2,3,3,3-heptafluoropropyl)-1λ5-1,1'(3H,3'H)-spirobi[2,1-benzoxarsole]

: 1401324-97-7
C₂₆H₈AsF₂₈IO₂

Guidance literature:: 2-[3,3-bis(1,1,2,2,3,3,3-heptafluoropropyl)-2,1-benzoxarsol-1(3H)-yl]-α,α-bis(1,1,2,2,3,3,3-heptafluoropropyl)benzenemethanol; tert.-butyl lithium; In diethyl ether; pentane; at -78 - 20 ℃; for 1h; Inert atmosphere;

With iodine; In diethyl ether; pentane; at -78 - 0 ℃; for 1h;
DOI:10.1021/ic3014893

Reference yield:

: 559-91-1
1-phenylperfluorobutan-1-one

: 1257079-30-3
4-(2-bromophenyl)-1,1,1,2,2,3,3,5,5,6,6,7,7,7-tetradecafluoroheptan-4-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrahydrofuran / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / hexane / 0 - 20 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; 1.1: Cannizzaro-type reaction;
DOI:10.1039/c0dt00539h