Anhydro Pridinol Hydrochloride

Base Information

• Chemical Name: Anhydro Pridinol Hydrochloride
• CAS No.: 13150-57-7
• Molecular Formula: C20H23 N
• Molecular Weight: 277.4033
• Hs Code.: 2933399090
• Mol file: 13150-57-7.mol

Synonyms:Piperidine,1-(3,3-diphenyl-2-propenyl)- (9CI); Piperidine, 1-(3,3-diphenylallyl)-(6CI,8CI)

Chemical Property of Anhydro Pridinol Hydrochloride

Chemical Property:

• Vapor Pressure: 2.1E-07mmHg at 25°C
• Boiling Point: 424.2°C at 760 mmHg
• Flash Point: 186.8°C
• PSA: 3.24000
• Density: 1.025g/cm³
• LogP: 4.54210

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Anhydro Pridinol Hydrochloride is a reagent commonly used in synthetic preparations.

Technology Process of Anhydro Pridinol Hydrochloride

There total 9 articles about Anhydro Pridinol Hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

1,1-Diphenyl-1-piperidino-2-propene (83314-35-6) → 1,1-Diphenyl-3-piperidino-1-propene (13150-57-7)

Guidance literature:

at 180 ℃; for 20h;

DOI:10.1002/ardp.19823150904

Reference yield:

piperidine (110-89-4) + 1,1-diphenyl-1,2-propadiene (14251-57-1) → 1,1-Diphenyl-3-piperidino-1-propene (13150-57-7)

Guidance literature:

With [3IP^tBuPd(allyl)]OTf; In benzene-d6; at 25 ℃; for 20h; Glovebox; Inert atmosphere; Sealed tube;

DOI:10.1039/c3ra43870h

Reference yield:

Pridinol (511-45-5) → 1,1-Diphenyl-3-piperidino-1-propene (13150-57-7)

Guidance literature:

With hydrogenchloride; acetic acid;

upstream raw materials:

Pridinol

1,1-Diphenyl-1-piperidino-2-propene

piperidine

α-bromo-α-phenylbenzeneacetonitrile

Downstream raw materials:

fenpiprane

Refernces

• 1、 Bersch, Hans-Werner,Rissmann, Ruediger,Schon, Dietmar. "Isomerizations of Tertiary Allylamines and Ring Expanding Rearrangements by Quaternization". . p. 749 - 760. Retrieved 2007/10/02.