C₄₆H₄₆N₂O₄S₃

Base Information

• Chemical Name: C₄₆H₄₆N₂O₄S₃
• CAS No.: 1375873-34-9
• Molecular Formula: C₄₆H₄₆N₂O₄S₃
• Molecular Weight: 787.08
• Mol file: 1375873-34-9.mol

Synonyms:C₄₆H₄₆N₂O₄S₃

Chemical Property of C₄₆H₄₆N₂O₄S₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₆H₄₆N₂O₄S₃

There total 3 articles about C₄₆H₄₆N₂O₄S₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

C50H54N2O4S3 → C46H46N2O4S3 (1375873-34-9)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2014.09.039

Reference yield:

N,N-bis(4-hexyloxyphenyl)-4-bromophenylamine (1092363-75-1) → C46H46N2O4S3 (1375873-34-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium; Trimethyl borate / tetrahydrofuran / -78 - 20 °C

1.2: 20 °C

2.1: tri-tert-butylphosphonium tetrafluoroborate; sodium carbonate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / toluene; water / 5 h / 60 °C

3.1: trifluoroacetic acid / dichloromethane / 20 °C / Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; n-butyllithium; Trimethyl borate; tri-tert-butylphosphonium tetrafluoroborate; sodium carbonate; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; water; toluene;

DOI:10.1016/j.tet.2014.09.039

Reference yield:

4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-(4-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline (1221821-41-5) → C46H46N2O4S3 (1375873-34-9)

Guidance literature:

Multi-step reaction with 2 steps

1: tri-tert-butylphosphonium tetrafluoroborate; sodium carbonate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / toluene; water / 5 h / 60 °C

2: trifluoroacetic acid / dichloromethane / 20 °C / Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butylphosphonium tetrafluoroborate; sodium carbonate; trifluoroacetic acid; In dichloromethane; water; toluene;

DOI:10.1016/j.tet.2014.09.039

upstream raw materials:

N,N-bis(4-hexyloxyphenyl)-4-bromophenylamine

4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-(4-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline