methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

Base Information

• Chemical Name: methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside
• CAS No.: 280569-43-9
• Molecular Formula: C₂₁H₂₅NO₅
• Molecular Weight: 371.433
• Mol file: 280569-43-9.mol

Synonyms:methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

Chemical Property of methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside

There total 1 articles about methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

(2R,4aR,6S,7S,8S,8aS)-7-Azido-8-benzyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine → methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside (280569-43-9)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 1.5h;

DOI:10.1080/07328300008544079

Reference yield: 85.0%

phthalic monoacid monomethyl ester chloride (4397-55-1) + methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside (280569-43-9) → methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-altropyranoside (280569-44-0)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 16h;

DOI:10.1080/07328300008544079

Reference yield: 76.0%

trifluoroacetyl chloride (76-02-8) + methyl 2-amino-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-altropyranoside (280569-43-9) → methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-trichloroacetamido-α-D-altropyranoside (280569-46-2)

Guidance literature:

With triethylamine; In dichloromethane; for 1h;

DOI:10.1080/07328300008544079

Downstream raw materials:

methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-tetrachlorophthalimido-α-D-altropyranoside

methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-phthalimido-α-D-altropyranoside

methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-trichloroacetamido-α-D-altropyranoside

methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-altropyranoside