Technology Process of 3-(4,5-dimethoxy-2-methyl-3,6-dioxo cyclohexa-1,4-dienyl)propyl nitrate
There total 4 articles about 3-(4,5-dimethoxy-2-methyl-3,6-dioxo cyclohexa-1,4-dienyl)propyl nitrate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
ammonium cerium (IV) nitrate;
In
water; acetonitrile;
at 0 ℃;
for 3h;
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 16 h / 0 - 20 °C
1.2: 0.5 h / 0 °C
2.1: triethylamine; dmap / dichloromethane / 5 h / 0 °C
3.1: tetrabutylammonium nitrate; sodium nitrate / acetic acid butyl ester; acetonitrile / 16 h / 90 °C
4.1: ammonium cerium (IV) nitrate / acetonitrile; water / 3 h / 0 °C
With
dmap; sodium nitrate; ammonium cerium (IV) nitrate; tetrabutylammonium nitrate; triethylamine; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; dichloromethane; acetic acid butyl ester; water; acetonitrile;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: triethylamine; dmap / dichloromethane / 5 h / 0 °C
2: tetrabutylammonium nitrate; sodium nitrate / acetic acid butyl ester; acetonitrile / 16 h / 90 °C
3: ammonium cerium (IV) nitrate / acetonitrile; water / 3 h / 0 °C
With
dmap; sodium nitrate; ammonium cerium (IV) nitrate; tetrabutylammonium nitrate; triethylamine;
In
dichloromethane; acetic acid butyl ester; water; acetonitrile;
