(E)-β-styryl phenyl selenone

Base Information

• Chemical Name: (E)-β-styryl phenyl selenone
• CAS No.: 108415-83-4
• Molecular Formula: C₁₄H₁₂O₂Se
• Molecular Weight: 291.208
• Mol file: 108415-83-4.mol

Synonyms:(E)-β-styryl phenyl selenone

Chemical Property of (E)-β-styryl phenyl selenone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-β-styryl phenyl selenone

There total 1 articles about (E)-β-styryl phenyl selenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(E)-phenyl(styryl)selane (60466-40-2) → (E)-β-styryl phenyl selenone (108415-83-4)

Guidance literature:

With dipotassium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In methanol; at 25 ℃; for 6h;

DOI:10.1016/S0040-4020(01)82071-8

Reference yield: 99.0%

(E)-β-styryl phenyl selenone (108415-83-4) + ethyl phenylcyanoacetate (4553-07-5) → ethyl 2-cyano-2,3-diphenyl-4-(phenylselenonyl)-butanoate (1180679-02-0)

Guidance literature:

With C₂₉H₃₀F₆N₄O₂; In toluene; at 50 ℃; for 48h; stereoselective reaction; Molecular sieve;

DOI:10.1002/adsc.200900222

Reference yield: 99.0%

5-hydroxypentylamine (2508-29-4) + (E)-β-styryl phenyl selenone (108415-83-4) → 5-(2-phenyl-1-aziridinyl)-1-pentanol (1244770-96-4)

Guidance literature:

In toluene; at 20 ℃; for 24h; chemoselective reaction; Molecular sieve;

DOI:10.1016/j.tet.2010.06.055

upstream raw materials:

(E)-phenyl(styryl)selane

Downstream raw materials:

(2-methoxy-2-phenylethyl)(methyl)sulfane

1,2-bis(methylthio)phenylethane

α-methoxystyrene

(E)-(2-methoxyvinyl)benzene

Refernces

• 1、 Bagnoli, Luana,Scarponi, Catalina,Testaferri, Lorenzo,Tiecco, Marcello. "Preparation of both enantiomers of cyclopropane derivatives from the reaction of vinyl selenones with di-(-)-bornyl malonate". experimental part. p. 1506 - 1514. Retrieved 2009/12/01.