7-O-acetyl-streptol

Base Information

Chemical Name:7-O-acetyl-streptol
CAS No.:857633-06-8
Molecular Formula:C₉H₁₄O₆
Molecular Weight:218.207
Hs Code.:

Synonyms:7-O-acetyl-streptol

Suppliers and Price of 7-O-acetyl-streptol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 7-O-acetyl-streptol

Chemical Property:

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Technology Process of 7-O-acetyl-streptol

There total 8 articles about 7-O-acetyl-streptol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1204745-32-3
(1S,2R,3S,4R)-5-acetoxymethyl-1-O-tert-butyldimethylsilyl-2,3-[(2R,3R)-2,3-dimethoxybutan-2,3-dioxy]-5-cyclohexene-1,2,3,4-tetraol

: 857633-06-8,400867-98-3
7-O-acetyl-streptol

Guidance literature:: With water; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1055/s-0029-1218540

Reference yield: 78.0%

: 75-36-5
acetyl chloride

: 111136-25-5
α-valienol

: 857633-06-8,400867-98-3
7-O-acetyl-streptol

Guidance literature:: With 2,4,6-trimethyl-pyridine; at 20 ℃; for 15h; regioselective reaction; Cooling;
DOI:10.1055/s-0030-1260547

Reference yield:

: 1323271-55-1
C₁₈H₃₄O₁₀

: 857633-06-8,400867-98-3
7-O-acetyl-streptol

Guidance literature:: Multi-step reaction with 6 steps

1.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

1.2: 0.25 h / -78 °C / Inert atmosphere

2.1: sodium tetrahydroborate / methanol / 0.5 h / 20 °C

3.1: dimethyl sulfoxide; trifluoroacetic anhydride / dichloromethane / 5 h / -78 °C / Molecular sieve; Inert atmosphere

3.2: -78 - 20 °C / Inert atmosphere

4.1: cerium(III) chloride heptahydrate / methanol / 1 h / -20 °C

4.2: -20 °C

5.1: trifluoroacetic acid / water / 0.5 h / 20 °C

6.1: 2,4,6-trimethyl-pyridine / 15 h / 20 °C / Cooling

With 2,4,6-trimethyl-pyridine; sodium tetrahydroborate; cerium(III) chloride heptahydrate; dimethyl sulfoxide; trifluoroacetic acid; trifluoroacetic anhydride; lithium diisopropyl amide; In tetrahydrofuran; methanol; hexane; dichloromethane; water;
DOI:10.1055/s-0030-1260547