Technology Process of (2,2'-bibenzimidazole)dichlorobis(triphenylphosphine)rhenium(III) chloride
There total 1 articles about (2,2'-bibenzimidazole)dichlorobis(triphenylphosphine)rhenium(III) chloride which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
triphenylphosphine;
In
chloroform;
a suspension of PPh3 and 2,2'-bibenzimidazole in CHCl3 heated to the boiling point, and ReOCl3(PPh3)2 added; mixture refluxed for 2.5 h; filtered hot; evaporation yields a sticky dark-red material; upon dropwise addition of diethyl ether, a red powder obtained, which filtered and washed with diethyl ether; crystals obtained by slow diffusion of diethyl ether into a CH2Cl2 soln.;
DOI:10.1016/j.poly.2004.01.012
