trichlorooxobis(triphenylphosphine)rhenium(V)

Base Information

Chemical Name:trichlorooxobis(triphenylphosphine)rhenium(V)
CAS No.:34248-12-9
Molecular Formula:C₃₆H₃₀Cl₃OP₂Re
Molecular Weight:833.147
Hs Code.:

Synonyms:trichlorooxobis(triphenylphosphine)rhenium(V)

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Chemical Property of trichlorooxobis(triphenylphosphine)rhenium(V)

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Technology Process of trichlorooxobis(triphenylphosphine)rhenium(V)

There total 7 articles about trichlorooxobis(triphenylphosphine)rhenium(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: ammonium perrhenate

: 603-35-0
triphenylphosphine

: 34248-12-9
trichlorooxobis(triphenylphosphine)rhenium(V)

Guidance literature:: In water; acetic acid; PPh3 dissolved at 90°C in glacial AcOH, soln. of ammonium perrhenate in concd. HCl added dropwise over 10 min, allowed to stay at 90°C overnight; ppt. filtered off, washed (AcOH and Et2O); elem. anal.;
DOI:10.1039/b001600o

Reference yield: 90.0%

: 603-35-0
triphenylphosphine

: tetrabutylammonium perrhenate

: 34248-12-9
trichlorooxobis(triphenylphosphine)rhenium(V)

Guidance literature:: In hydrogenchloride; acetic acid; soln. of (C4H9)4NReO4 in concd. HCl slowly added to soln. of P(C6H5)3 inacetic acid under stirring, dropping funnel rinsed with glacial CH3COOH , mixt. stirred for 5 h; ppt. filtered off, washed with glacial CH3COOH and diethyl ether, dried overnight in vac. desiccator over P2O5;
DOI:10.1081/SIM-200047553

Reference yield: 85.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: sodium azide

: 10466-65-6
potassium perrhenate

: 603-35-0
triphenylphosphine

: 34248-12-9
trichlorooxobis(triphenylphosphine)rhenium(V)

: 412304-56-4,25685-08-9
[ReNCl2(PPh3)2]

Guidance literature:: In water; acetone; KReO4 and aq. HCl refluxed for 30 min, aq. NaN3 added, mixt. refluxed for 30 min, soln. of P(C6H5)3 in acetone added, soln. refluxed for 30 min,longer refluxing time leads to oxotrichloro complex; ppt. collected by vac. filtration, washed with warm water, ethanol, and acetone;
DOI:10.1081/SIM-200047553