1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

Base Information

Chemical Name:1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene
CAS No.:180966-19-2
Molecular Formula:C₆₀H₁₀₂N₆O₉S₆
Molecular Weight:1243.9
Hs Code.:

Synonyms:1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

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Chemical Property of 1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

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Technology Process of 1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

There total 9 articles about 1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 4422-95-1
1,3,5-benzene tris(carbonyl chloride)

: 180965-98-4
5-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadecane

: 180966-19-2
1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

Guidance literature:: With triethylamine; In tetrahydrofuran; for 2.5h; Ambient temperature;
DOI:10.1039/p19960001553

Reference yield:

: 5279-23-2
3,3‘-(benzylazanediyl)bis(propan-1-ol)

: 180966-19-2
1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

Guidance literature:: Multi-step reaction with 5 steps

1: 92 percent / SOCl₂ / CH₂Cl₂ / 1.) room temp., overnight, 2.) reflux, 2 h

2: 58 percent / Cs₂CO₃ / dimethylformamide / 24 h / 85 °C

3: 96 percent / K₂CO₃ / benzene / 12 h / Heating

4: 72 percent / Zn, AcOH / 2 h / Ambient temperature

5: 92 percent / Et₃N / tetrahydrofuran / 2.5 h / Ambient temperature

With thionyl chloride; potassium carbonate; caesium carbonate; acetic acid; triethylamine; zinc; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1039/p19960001553

Reference yield:

: 102073-95-0
di-(3-chloropropyl)amine

: 180966-19-2
1,3,5-tris[(13-tert-butoxycarbonyl-1,9-dithia-5,13-diazacyclohexadec-5-yl)carbonyl]benzene

Guidance literature:: Multi-step reaction with 7 steps

1: 77 percent / 10percent aq. NaOH / CH₂Cl₂ / 4 h

2: 80 percent / dimethylformamide / 48 h / Ambient temperature

3: 74 percent / NaOMe / methanol / 0.08 h

4: 58 percent / Cs₂CO₃ / dimethylformamide / 24 h / 85 °C

5: 96 percent / K₂CO₃ / benzene / 12 h / Heating

6: 72 percent / Zn, AcOH / 2 h / Ambient temperature

7: 92 percent / Et₃N / tetrahydrofuran / 2.5 h / Ambient temperature

With sodium hydroxide; sodium methylate; potassium carbonate; caesium carbonate; acetic acid; triethylamine; zinc; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1039/p19960001553