1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine

Base Information

• Chemical Name: 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine
• CAS No.: 54918-94-4
• Molecular Formula: C₁₅H₁₂Cl₂N₂O₃
• Molecular Weight: 339.178
• Mol file: 54918-94-4.mol

Synonyms:1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine

Chemical Property of 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine

There total 6 articles about 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

salicylaldehyde (90-02-8) + 2,4-dichlorophenoxyacetylhydrazine (28236-62-6) → 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine (54918-94-4)

Guidance literature:

at 20 ℃; for 0.25h; Milling; Green chemistry;

DOI:10.1016/j.saa.2014.05.062

Reference yield: 93.0%

2-methyl-benzyl alcohol (89-95-2) + 2,4-dichlorophenoxyacetylhydrazine (28236-62-6) → 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine (54918-94-4)

Guidance literature:

at 75 ℃; for 0.025h; microwave irradiation;

Reference yield:

methyl 2,4-dichlorophenoxyacetate (1928-38-7) → 1-[(2,4-dichlorophenoxy)acetyl]-2-(2-hydroxybenzylidene)hydrazine (54918-94-4)

Guidance literature:

Multi-step reaction with 2 steps

1: N₂H₄*H₂O / ethanol / Heating

2: ethanol / Heating

With hydrazine hydrate; In ethanol;

DOI:10.1248/cpb.22.2778

upstream raw materials:

salicylaldehyde

2,4-dichlorophenoxyacetylhydrazine

2-methyl-benzyl alcohol

2,4-Dichlorophenoxyacetic acid

Downstream raw materials:

Cu₂(Cl₂C₆H₃OCH₂C(O)NHNCHC₆H₄O)2(ONO₂)⁽¹⁺⁾*NO₃^(1-)=[Cu₂(Cl₂C₆H₃OCH₂C(O)NHNCHC₆H₄O)2(ONO₂)]NO₃

Cu₂(Cl₂C₆H₃OCH₂C(O)NNCHC₆H₄O)2(C₂H₅OH)(H₂O)=[Cu₂(Cl₂C₆H₃OCH₂C(O)NNCHC₆H₄O)2(C₂H₅OH)(H₂O)]

Cu₂(Cl₂C₆H₃OCH₂C(O)NNCHC₆H₄O)2(H₂O)2=[Cu₂(Cl₂C₆H₃OCH₂C(O)NNCHC₆H₄O)2(H₂O)2]