Methyl (2,4-dichlorophenoxy)acetate

Base Information

• Chemical Name: Methyl (2,4-dichlorophenoxy)acetate
• CAS No.: 1928-38-7
• Molecular Formula: C9H8 Cl2 O3
• Molecular Weight: 235.067
• Hs Code.: 2918990090
• European Community (EC) Number: 217-670-7,811-177-6
• NSC Number: 9399
• UNII: SG8721Q1O5
• DSSTox Substance ID: DTXSID6041349
• Nikkaji Number: J7.820D
• Wikidata: Q22329230
• ChEMBL ID: CHEMBL1327631
• Mol file: 1928-38-7.mol

Synonyms:2,4-D methyl ester;2,4-dichlorophenoxyacetic acid methyl ester;2,4-DMe

Chemical Property of Methyl (2,4-dichlorophenoxy)acetate

Chemical Property:

• Vapor Pressure: 0.000385mmHg at 25°C
• Boiling Point: 298.3°Cat760mmHg
• Flash Point: 124.1°C
• PSA: 35.53000
• Density: 1.352g/cm³
• LogP: 2.54520
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 233.9850495
• Heavy Atom Count: 14
• Complexity: 199

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): F,Xn,N
• Hazard Codes: F,Xn,N

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Herbicides, Chlorophenoxy
• Canonical SMILES: COC(=O)COC1=C(C=C(C=C1)Cl)Cl

Technology Process of Methyl (2,4-dichlorophenoxy)acetate

There total 16 articles about Methyl (2,4-dichlorophenoxy)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.32%

methyl 2-phenoxyacetate (2065-23-8) → methyl 2,4-dichlorophenoxyacetate (1928-38-7)

Guidance literature:

With 2-ethylthiazole; thionyl chloride; tin(IV) chloride; at 20 ℃; for 0.5h; Reagent/catalyst;

Reference yield: 99.28%

n-propyl phenoxyacetate (6212-47-1) → methyl 2,4-dichlorophenoxyacetate (1928-38-7)

Guidance literature:

With phenyl mesityl sulfide; chlorine; zinc(II) chloride; at -20 ℃; for 0.5h; Reagent/catalyst;

Reference yield: 99.2%

methyl chloroacetate (96-34-4) + 2,4-dichlorophenol (120-83-2,40477-79-0) → methyl 2,4-dichlorophenoxyacetate (1928-38-7)

Guidance literature:

With potassium fluoride; potassium iodide; at 120 ℃; for 24h; Reagent/catalyst; Time;

upstream raw materials:

methanol

2,4-Dichlorophenoxyacetic acid

methyl iodide

2,4-dichlorophenoxyacetic acid dimethylamine

Downstream raw materials:

N-[(2,4-dichloro-phenoxy)-acetyl]-N-methyl-D-glucamine

Bromo-(2,4-dichloro-phenoxy)-acetic acid methyl ester

2,4-dichlorophenoxythioacetamide

2,4-dichlorophenoxyacetylhydrazine